Transition-metal-catalyzed direct arylation of (hetero)arenes by C-H bond cleavage.
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Summary
P palladium and ruthenium catalysts have been described that enable the direct arylation of (hetero)arenes with challenging coupling partners--including electrophilic aryl chlorides and tosylates as well as simple arenes in cross-dehydrogenative arylations.
- Type
- review
- Published
- 2009-12-21
- Cited by
- 2,269
- References
- 397
- OpenAlex
- https://openalex.org/W2038974680
- Semantic Scholar
- https://api.semanticscholar.org/CorpusID:205354837
Keywords
Transition metal, Aryl, Catalysis, Chemistry, Cleavage (geology)
References
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- Valsartan
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- Aromatic substitution of styrene-palladium chloride complex
- Palladium-catalyzed ring-forming reactions: Methods and applications
- Palladium‐Catalyzed C ? H Activation of Methoxy Groups: A Facile Synthesis of Substituted 6H‐Dibenzo[b,d]pyrans
Cited by
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- Rhodium(III)-catalyzed oxidative coupling of 5-aryl-1H-pyrazoles with alkynes and acrylates.
- Pd(OAc)2/o-chloranil/M(OTf)n: a catalyst for the direct C-H arylation of polycyclic aromatic hydrocarbons with boryl-, silyl-, and unfunctionalized arenes.
- Pd-catalysed synthesis of isoquinolinones and analogues via C-H and N-H bonds double activation.
- Palladium-catalyzed intramolecular C-H arylation of arenes using tosylates and mesylates as electrophiles.
- N-Heterocyclic carbene dichotomy in Pd-catalyzed acylation of aryl chlorides via C-H bond functionalization.
- Regioselective threefold aromatic substitution of benzoic acid derivatives by dearomatization, regioselective functionalization, and rearomatization.
- Purinyl N1-Directed Aromatic C–H Oxidation in 6-Arylpurines and 6-Arylpurine Nucleosides
- "On water", phosphine-free palladium-catalyzed room temperature C-H arylation of indoles.
- Enantioselective Arylative Dearomatization of Indoles via Pd-Catalyzed Intramolecular Reductive Heck Reactions.
- Regiospecific Benzoylation of Electron-Deficient N-Heterocycles with Methylbenzenes via a Minisci-Type Reaction.
- Cobalt(III)-Catalyzed Aryl and Alkenyl C-H Aminocarbonylation with Isocyanates and Acyl Azides.
- Iron-catalyzed direct α-arylation of ethers with azoles.
- Copper-Catalyzed 8-Amido Chelation-Induced Remote C-H Amination of Quinolines.
- Rhodium-Catalyzed C6-Selective C-H Borylation of 2-Pyridones.
- Traceless directing group mediated branched selective alkenylation of unbiased arenes.
- Visible Light as a Sole Requirement for Intramolecular C(sp3)-H Imination.
- Asymmetric Iron-Catalyzed C-H Alkylation Enabled by Remote Ligand meta-Substitution.
- Halo-substituted benzenesulfonyls and benzenesulfinates: convenient sources of arenes in metal-catalyzed C-C bond formation reactions for the straightforward access to halo-substituted arenes.
- Palladium-Catalyzed Regioselective Olefination of O-Acetyl Cyanohydrins.
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