Nickel-Catalyzed Directed Cross-Electrophile Coupling of Phenolic Esters with Arylmethyl Trimethylammonium Triflates.
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Summary
In this context, polycyclic aryl-activated alkyl ammonium triflates are used as the electrophilic aryal-activatedAlkylating agent in the nickel-catalyzed hydroxyl- or sulfonamide-directed cross-electrophile coupling reaction with an array of phenyl benzoates, allowing for the synthesis of various aryL ketones under mild conditions.
- Type
- article
- Published
- 2023-07-11
- Cited by
- 4
- References
- 22
- OpenAlex
- https://openalex.org/W4383879212
- Semantic Scholar
- https://api.semanticscholar.org/CorpusID:259831535
Keywords
Electrophile, Aryl, Chemistry, Catalysis, Sulfonamide
References
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- Nickel-Catalyzed Reductive Couplings
- Palladium-Catalyzed Suzuki-Miyaura Coupling of Aryl Esters.
- Pd-PEPPSI: A General Pd-NHC Precatalyst for Suzuki–Miyaura Cross-Coupling of Esters by C–O Cleavage
- Rapidly Activating Pd-Precatalyst for Suzuki–Miyaura and Buchwald–Hartwig Couplings of Aryl Esters
- Recent Advances in Nickel Catalysis Enabled by Stoichiometric Metallic Reducing Agents
- Ligand-Controlled Chemoselective C(acyl)-O Bond vs C(aryl)-C Bond Activation of Aromatic Esters in Nickel Catalyzed C(sp2)-C(sp3) Cross-Couplings.
- Pd-PEPPSI: Water-Assisted Suzuki−Miyaura Cross-Coupling of Aryl Esters at Room Temperature using a Practical Palladium-NHC (NHC=N-Heterocyclic Carbene) Precatalyst
- Switchable Selectivity in the Pd-Catalyzed Alkylative Cross-Coupling of Esters.
- Reductive Coupling between C-N and C-O Electrophiles.
- Nickel-Catalyzed Enantioselective Reductive Cross-Coupling Reactions
- Development of Transition-Metal-Catalysed Cross-Coupling Reactions through Ammonium C-N Bond Cleavage.
- Recent Methodologies That Exploit Oxidative Addition of C–N Bonds to Transition Metals
- Nickel-Catalyzed Directed Cross-Electrophile Coupling of Phenolic Esters with Alkyl Bromides.
- Nickel-Catalyzed, Stereospecific C–C and C–B Cross-Couplings via C–N and C–O Bond Activation
- Nickel-Catalyzed Reductive Cross-Couplings: New Opportunities for Carbon–Carbon Bond Formations through Photochemistry and Electrochemistry
Cited by
- Nickel-Catalyzed Inter- and Intramolecular Reductive Cross-Coupling Reactions of Arylbenzylammonium Salts through Highly Site-Selective C–N Bond Cleavage
- Magnesium-Mediated Cross-Electrophile Couplings of Aryl 2-Pyridyl Esters with Aryl Bromides for Ketone Synthesis through In Situ-Formed Arylmagnesium Intermediates.
- Nickel-Catalyzed Reductive Alkylation of Pyridines via C-N Bond Activation.
- Electrochemically Driven Nickel-Catalyzed Synthesis of Aryl Alkyl Ketones by the Cross-Coupling of Carboxylic Esters with Alkylpyridinium Salts.
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