Recent advances in the application of Selectfluor as a "fluorine-free" functional reagent in organic synthesis.
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Summary
A brief history of Selectfluor as a transition metal oxidant, fluorine cation and radical initiator in "fluorine-free" functionalizations over the last five years is presented.
- Type
- review
- Published
- 2020-02-18
- Cited by
- 55
- References
- 83
- OpenAlex
- https://openalex.org/W3008930314
- Semantic Scholar
- https://api.semanticscholar.org/CorpusID:211159543
Keywords
Selectfluor, Fluorine, Reagent, Tetrafluoroborate, Octane
References
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- Monofluorination of Organic Compounds: 10 Years of Innovation.
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- Recent Advances in the Application of SelectfluorTMF-TEDA-BF4 as a Versatile Mediator or Catalyst in Organic Synthesis
- Recent progress in asymmetric fluorination and trifluoromethylation reactions.
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Cited by
- Synthesis and Diels–Alder Reactivity of 4-Fluoro-4-Methyl-4H-Pyrazoles
- Metal‐Free Synthesis of Imidazo[2,1‐ b ]thiazoles from Thioimidazoles and Ketones Mediated by Selectfluor
- Efficient cleavage of tertiary amide bonds via radical–polar crossover using a copper(ii) bromide/Selectfluor hybrid system
- Metal-free direct C(sp3)−H functionalization of 2-alkylthiobenzoic acid to access 1,3-benzooxathiin-4-one
- Blue-light-promoted radical C–H azolation of cyclic nitrones enabled by Selectfluor®
- C2-arylacylation of 2H-benzothiazoles with methyl arenes via Selectfluor oxidation
- Highly Stereoselective Intramolecular Carbofluorination of Internal α,β-Ynones Promoted by Selectfluor.
- Metal‐Free Selective C−S Bond Cleavage of Thioethers to Access β‐Alkoxy Carbonyl Compounds
- Amide-assisted α-C(sp3)–H acyloxyation of organic sulfides to access α-acyloxy sulfides
- C–C Bond Fluorination via Manganese Catalysis
- PhB(OH)2-Promoted Electrochemical Sulfuration-Formyloxylation of Styrenes and Selectfluor-Mediated Oxidation-Olefination.
- NFSI-catalyzed S‒S bond exchange reaction for the synthesis of unsymmetrical disulfides
- New Halogen-Containing Drugs Approved by FDA in 2021: An Overview on Their Syntheses and Pharmaceutical Use
- Copper(II)-Catalyzed Selective CAr-H Bond Formylation: Synthesis of Dialdehyde Aniline
- Selectfluor-Promoted Α-Methylenation of Aromatic Ketones to Terminal Olefins Using Acetonitrile as One Carbon Source
- Selectfluor and TBAX (Cl, Br) Mediated Oxidative Chlorination and Bromination of Olefins
- Selectfluor®-enabled photochemical selective C(sp3)-H(sulfonyl)amidation.
- Benzoates as photosensitization catalysts and auxiliaries in efficient, practical, light-powered direct C(sp3)–H fluorinations
- Direct substitution of the hydroxy group of alcohols with N-nucleophiles mediated by the substoichiometric amount of Selectfluor F-TEDA-BF as a precatalyst under mild reaction conditions
- Direct and Regioselective C−H Selenylation of 4‐Aminocoumarin Derivatives Mediated by Selectfluor®
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