Modular chemistry: secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks.
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Summary
Consideration of the geometric and chemical attributes of the SBUs and linkers leads to prediction of the framework topology, and in turn to the design and synthesis of a new class of porous materials with robust structures and high porosity.
- Type
- article
- Published
- 2001-02-17
- Cited by
- 4,321
- References
- 38
- OpenAlex
- https://openalex.org/W2164043498
- Semantic Scholar
- https://api.semanticscholar.org/CorpusID:1275169
Keywords
SBus, Porosity, Modular design, Ligand (biochemistry), Carboxylate
References
- Design and synthesis of metal-carboxylate frameworks with permanent microporosity
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- From Condensed Lanthanide Coordination Solids to Microporous Frameworks Having Accessible Metal Sites
- Dinuclear Paddle-Wheel Copper(II) Carboxylates in the Catalytic Oxidation of Carboxylic Acids. Unusual Polymeric Chains Found in the Single-Crystal X-ray Structures of [Tetrakis(&mgr;-1-phenylcyclopropane-1-carboxylato-O,O')bis(ethanol-O)dicopper(II)] and catena-Poly[[bis(&mgr;-diphenylacetato-O:O')
- Interpenetrating Nets: Ordered, Periodic Entanglement.
- Turning Down the Heat: Design and Mechanism in Solid-State Synthesis
- Inorganic crystal engineering using self-assembly of tailored building-blocks
- Structural Diversity in the Carbamato Chemistry of Zinc: X-ray Single-Crystal Structures of [(Me2NCH2)2Zn(O2CN(C2H5)2)2] and [C5H5NZn2Me(O2CN(C2H5)2)3]
- Interwoven Metal-Organic Framework on a Periodic Minimal Surface with Extra-Large Pores
- Bis(isonicotinato)iron(II): a rare, neutral three-dimensional iron coordination polymer
- Functional Micropore Chemistry of Crystalline Metal Complex-Assembled Compounds
- Highly Porous and Stable Metal−Organic Frameworks: Structure Design and Sorption Properties
- Supramolecular Isomerism in Coordination Polymers: Conformational Freedom of Ligands in [Co(NO3)2(1,2‐bis(4‐pyridyl)ethane)1.5]n
- Crystal structures. I. Patterns and symmetry
- Coordination Polymers of Co(NCS)2 with Pyrazine and 4,4‘-Bipyridine: Syntheses and Structures
- Open-Framework Inorganic Materials.
- Zeolite-like crystal structure of an empty microporous molecular framework
- Selective Guest Binding by Tailored Channels in a 3-D Porous Zinc(II)−Benzenetricarboxylate Network
- Variable Pore Size, Variable Chemical Functionality, and an Example of Reactivity within Porous Phenylacetylene Silver Salts
Cited by
- Constructing terbium co-ordination polymers of 4,4'-bipyridine-N,N'-dioxide by means of diffusion solvent mixtures.
- Homochiral 3D lanthanide coordination networks with an unprecedented 4(9)6(6) topology.
- Ternary nets formed by self-assembly of triangles, squares, and tetrahedra.
- Reversible single-crystal-to-single-crystal guest exchange in a 3-D coordination network based on a zinc porphyrin.
- An EXAFS study of the formation of a nanoporous metal-organic framework: evidence for the retention of secondary building units during synthesis.
- Crystal engineering of coordination polymers using 4,4'-bipyridine as a bond between transition metal atoms.
- Functionalized coordination space in metal-organic frameworks.
- Metal-organic spheres as functional systems for guest encapsulation.
- Large H2 storage capacity of a new polyhedron-based metal-organic framework with high thermal and hygroscopic stability.
- Homochiral zinc phosphonates with layered and open framework structures using polycarboxylate as second linkers.
- Oriented nanoscale films of metal-organic frameworks by room-temperature gel-layer synthesis.
- Synthesis, characterisation and adsorption properties of a porous copper(II) 3D coordination polymer exhibiting strong binding enthalpy and adsorption capacity for carbon dioxide.
- Synthesis, ab initio X-ray powder diffraction crystal structure, and magnetic properties of Mn3(OH)2(C6H2O4S)2 metal-organic framework.
- Molecular tectonics: homochiral coordination networks based on combinations of a chiral neutral tecton with Hg(II), Cu(II) or Ni(II) neutral complexes as metallatectons.
- The role of boric acid in the synthesis of Eni Carbon Silicates.
- Synthesis and characterization of amine-functionalized mixed-ligand metal-organic frameworks of UiO-66 topology.
- Diaquabis5-carboxy-2-[(1H-1,2,4-triazol-1-yl)methyl]-1H-imidazole-4-carboxylatozinc
- Bimetallic Metal-Organic Frameworks: Probing the Lewis Acid Site for CO2 Conversion.
- Poly[[diaqua(3-carboxy-5-nitrobenzoato)(μ-5-nitrobenzene-1,3-dicarboxylato)neodymium(III)] 2.5-hydrate]
- Gas/vapour separation using ultra-microporous metal-organic frameworks: insights into the structure/separation relationship.
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