Dinuclear Paddle-Wheel Copper(II) Carboxylates in the Catalytic Oxidation of Carboxylic Acids. Unusual Polymeric Chains Found in the Single-Crystal X-ray Structures of [Tetrakis(&mgr;-1-phenylcyclopropane-1-carboxylato-O,O')bis(ethanol-O)dicopper(II)] and catena-Poly[[bis(&mgr;-diphenylacetato-O:O')
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Summary
The X-ray structures and spectroscopic and magnetic properties of tetrakis(diphenylacetato)dicopper(II) units, two extended-chain copper( II) carboxylates with dinuclear paddle-wheel subunits, are reported, and the dinuclear subunits are likely candidates for the catalytically active Cu species in copper(II)-catalyzed oxidation of carboxylic acids.
- Type
- article
- Published
- 1997-09-24
- Cited by
- 89
- References
- 0
- OpenAlex
- https://openalex.org/W1977885757
- Semantic Scholar
- https://api.semanticscholar.org/CorpusID:26362234
Keywords
Chemistry, Carboxylate, Triclinic crystal system, Crystallography, Copper
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