Dinuclear Paddle-Wheel Copper(II) Carboxylates in the Catalytic Oxidation of Carboxylic Acids. Unusual Polymeric Chains Found in the Single-Crystal X-ray Structures of [Tetrakis(&mgr;-1-phenylcyclopropane-1-carboxylato-O,O')bis(ethanol-O)dicopper(II)] and catena-Poly[[bis(&mgr;-diphenylacetato-O:O')

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Summary

The X-ray structures and spectroscopic and magnetic properties of tetrakis(diphenylacetato)dicopper(II) units, two extended-chain copper( II) carboxylates with dinuclear paddle-wheel subunits, are reported, and the dinuclear subunits are likely candidates for the catalytically active Cu species in copper(II)-catalyzed oxidation of carboxylic acids.

Type
article
Published
1997-09-24
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Keywords

Chemistry, Carboxylate, Triclinic crystal system, Crystallography, Copper

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