Molecular building blocks approach to the assembly of zeolite-like metal-organic frameworks (ZMOFs) with extra-large cavities.

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Summary

Two novel porous anionic zeolite-like metal-organic frameworks have been synthesized by metal-ligand-directed assembly of rigid and directional tetrahedral building units, InN4 synthesized in situ, and doubly deprotonated bis(bidentate) imidazoledicarboxylic acid ligands (HImDC) in the presence of different structure directing agents (SDAs).

Type
article
Published
2006-03-30
Cited by
412
References
18
Access
Open access

Keywords

Zeolite, Ligand (biochemistry), Deprotonation, Denticity, Metal-organic framework

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