Phosphomolybdic and phosphotungstic acids as efficient catalysts for the synthesis of bridged 1,2,4,5-tetraoxanes from β-diketones and hydrogen peroxide.
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Summary
The use of these catalysts made it possible to obtain bridged tetraoxanes from easily oxidizable benzoylacetone derivatives and α-unsubstituted β-diketones to form bridged 1,2,4,5-tetraoxane synthesis.
- Type
- article
- Published
- 2013-03-26
- Cited by
- 43
- References
- 71
- OpenAlex
- https://openalex.org/W2036118188
- Semantic Scholar
- https://api.semanticscholar.org/CorpusID:38000691
Keywords
Phosphomolybdic acid, Phosphotungstic acid, Hydrogen peroxide, Chemistry, Catalysis
References
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- Vibrational and electronic spectra of new liposoluble metalloporphyrins in a nonpolar noncoordinating solvent
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- Anthelmintic activity of artesunate against Fasciola hepatica in naturally infected sheep.
Cited by
- Peroxidation of β-diketones and β-keto esters with tert-butyl hydroperoxide in the presence of Cu(ClO4)2/SiO2
- Stereoelectronic source of the anomalous stability of bis-peroxides
- Organocatalytic peroxidation of malonates, β-ketoesters, and cyanoacetic esters using n-Bu4NI/t-BuOOH-mediated intermolecular oxidative C(sp3)–O coupling
- Six Peroxide Groups in One Molecule – Synthesis of Nine-Membered Bicyclic Silyl Peroxides
- Energetic Organic Peroxides – Synthesis and Characterization of 1,4‐Dimethyl‐2,3,5,6‐tetraoxabicyclo[2.2.1]heptanes
- Convenient synthesis of novel heteroatom-substituted quinolines via Friedländer annulation using phosphotungstic acid as a reusable catalyst
- Synthesis of five- and six-membered cyclic organic peroxides: Key transformations into peroxide ring-retaining products
- Manganese triacetate as an efficient catalyst for bisperoxidation of styrenes.
- Reactions of mono- and bicyclic enol ethers with the I2–hydroperoxide system
- Approach for the preparation of various classes of peroxides based on the reaction of triketones with H2O2: first examples of ozonide rearrangements.
- Synthesis and reactivity of 1,2-dioxolanes from β,γ-epoxy ketones.
- Elucidation of the in vitro and in vivo activities of bridged 1,2,4-trioxolanes, bridged 1,2,4,5-tetraoxanes, tricyclic monoperoxides, silyl peroxides, and hydroxylamine derivatives against Schistosoma mansoni.
- Transformation of 2-allyl-1,3-diketones to bicyclic compounds containing 1,2-dioxolane and tetrahydrofuran rings using the I2/H2O2 system
- Metodologias de síntese de tetraoxanos com potencial utilização em química medicinal
- Rearrangements of organic peroxides and related processes
- Cyclic peroxides as promising anticancer agents: in vitro cytotoxicity study of synthetic ozonides and tetraoxanes on human prostate cancer cell lines
- Stereoelectronic Chameleons: The Donor-Acceptor Dichotomy of Functional Groups.
- Stereoelectronic Control in the Ozone-Free Synthesis of Ozonides.
- A General and Practical Approach for the Synthesis of 1,2,4‐Trioxanes Catalyzed by Silica‐Ferric Chloride
- Stereoelectronic Interactions as a Probe for the Existence of the Intramolecular α-Effect.
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