Efficient and selective oxidation of sulfur mustard using singlet oxygen generated by a pyrene-based metal–organic framework
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Summary
This method was tested on the warfare agent sulfur mustard for the first time using 1O2 and a MOF catalyst, and it proved to be effective in oxidizing sulfur mustard to nontoxic products without forming the toxic sulfone by-product.
- Type
- article
- Published
- 2016-08-23
- Cited by
- 97
- References
- 68
- Access
- Open access
- OpenAlex
- https://openalex.org/W2513814813
- Semantic Scholar
- https://api.semanticscholar.org/CorpusID:38159182
Keywords
Sulfur mustard, Singlet oxygen, Sulfone, Sulfur, Oxidizing agent
References
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- Hydrolysis and biodegradation of the vesicant agent HT: Two potential approaches
- Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks
- Soil biotransformation of thiodiglycol, the hydrolysis product of mustard gas: understanding the factors governing remediation of mustard gas contaminated soil
- Rapid Nucleophilic/Oxidative Decontamination of Chemical Warfare Agents
- A homogeneous catalyst for selective O(2) oxidation at ambient temperature. diversity-based discovery and mechanistic investigation of thioether oxidation by the Au(III)Cl(2)NO(3)(thioether)/O(2) system.
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- Reticular synthesis and the design of new materials
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- Controlled unsteady state processes and technologies - An overview
- Reactions of VX, GD, and HD with Nanosize MgO
- Equilibria, Kinetics, and Mechanism in the Bicarbonate Activation of Hydrogen Peroxide: Oxidation of Sulfides by Peroxymonocarbonate
- Bicarbonate surfoxidants: micellar oxidations of aryl sulfides with bicarbonate-activated hydrogen peroxide.
Cited by
- Postsynthetic Incorporation of a Singlet Oxygen Photosensitizer in a Metal-Organic Framework for Fast and Selective Oxidative Detoxification of Sulfur Mustard.
- Catalytic degradation of chemical warfare agents and their simulants by metal-organic frameworks
- Toward a detoxification fabric against nerve gas agents: guanidine-functionalized poly[2-(3-butenyl)-2-oxazoline]/Nylon-6,6 nanofibers
- Metal-organic frameworks for the removal of toxic industrial chemicals and chemical warfare agents.
- Adsorption of a Catalytically Accessible Polyoxometalate in a Mesoporous Channel-type Metal–Organic Framework
- Atomistic Approach toward Selective Photocatalytic Oxidation of a Mustard-Gas Simulant: A Case Study with Heavy-Chalcogen-Containing PCN-57 Analogues.
- Synthesis of aryl-substituted pyridines via cyclization of N,N-dialkylanilines with ketoxime carboxylates under metal-organic framework catalysis
- Detoxification of a Sulfur Mustard Simulant Using a BODIPY-Functionalized Zirconium-Based Metal-Organic Framework.
- Singlet Fission within Diketopyrrolopyrrole Nanoparticles in Water
- Metal–organic frameworks as media for the catalytic degradation of chemical warfare agents
- Detoxification of Chemical Warfare Agents: From WWI to Multifunctional Nanocomposite Approaches
- Destruction of chemical warfare agent simulants by air and moisture stable metal NHC complexes.
- Thermally induced migration of a polyoxometalate within a metal-organic framework and its catalytic effects
- An Ultra-Robust and Crystalline Redeemable Hydrogen-Bonded Organic Framework for Synergistic Chemo-Photodynamic Therapy.
- Oxidation studies on mustard gas, and the first crystal structure of a metal-mustard gas complex
- Air Activated Self-Decontaminating Polydicyclopentadiene PolyHIPE Foams for Rapid Decontamination of Chemical Warfare Agents.
- Significant enhancement in hydrolytic degradation of sulfur mustard promoted by silver nanoparticles in the Ag NPs@HKUST-1 composites.
- Pyrene-based metal–organic framework NU-1000 photocatalysed atom-transfer radical addition for iodoperfluoroalkylation and (Z)-selective perfluoroalkylation of olefins by visible-light irradiation
- A dual-functional bimetallic-organic framework nanosensor for detection and decontamination of lachrymator in drinking water
- A Versatile Self-Detoxifying Material Based on Immobilized Polyoxoniobate for Decontamination of Chemical Warfare Agent Simulants.
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