Construction of a highly distorted benzene ring in a double helicene.
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Summary
A P-fused double helicene consisting of a highly distorted benzene ring, with a bending angle of 23°, has been synthesized by a tandem intramolecular phospha-Friedel-Crafts reaction.
- Type
- article
- Published
- 2014-12-15
- Cited by
- 87
- References
- 23
- OpenAlex
- https://openalex.org/W2121684978
- Semantic Scholar
- https://api.semanticscholar.org/CorpusID:31991937
Keywords
Helicene, Intramolecular force, Ring (chemistry), Benzene, Molecule
References
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- Fenestrane in der Synthese: einzigartige und inspirierende Grundgerüste
- Fenestranes in synthesis: unique and highly inspiring scaffolds.
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- The crystal structure of deuterated benzene
- Synthetic approaches to aromatic belts: building up strain in macrocyclic polyarenes.
Cited by
- Synthesis of a double helicene by a palladium-catalyzed cross-coupling reaction: structure and physical properties.
- Dibenzo[b,e]phosphindolizines synthesized by a ring-closing metathesis of benzo[b]phospholes with two vinyl tethers.
- A double hetero[4]helicene composed of two phenothiazines: synthesis, structural properties, and cationic states.
- New advances in nanographene chemistry.
- A facile and versatile approach to double N-heterohelicenes: tandem oxidative C-N couplings of N-Heteroacenes via cruciform dimers.
- π-Helicene auf ein Minimum reduziert: Zugang mithilfe einer mehrfachen Domino-Carbopalladierungs-Stille-Sequenz†
- π-Helicenes truncated to a minimum: access through a domino approach involving multiple carbopalladations and a Stille coupling.
- One-Pot Benzo[b]phosphole Synthesis through Sequential Alkyne Arylmagnesiation, Electrophilic Trapping, and Intramolecular Phospha-Friedel-Crafts Cyclization.
- Method for the Synthesis of Dibenzo[g,p]Chrysenes: Domino Friedel-Crafts-Type Cyclization of Difluoroethenes Bearing Two Biaryl Groups.
- Synthesis, Structures, and Properties of π-Extended Double Helicene: A Combination of Planar and Nonplanar π-Systems.
- Two-Step Synthesis of Boron-Fused Double Helicenes.
- Quantification of Aromaticity Based on Interaction Coordinates: A New Proposal.
- Rhodium(III)-Catalyzed Direct Coupling of Arylphosphine Derivatives with Heterobicyclic Alkenes: A Concise Route to Biarylphosphines and Dibenzophosphole Derivatives
- Silicon Spiro Double Helicene-like Compounds Based on Dithieno[2,3-b:3',2'-d]thiophene: Syntheses and Crystal Structures.
- Heterocyclic Nanographenes and Other Polycyclic Heteroaromatic Compounds: Synthetic Routes, Properties, and Applications.
- Reinvestigation of the photoreaction of 1,4-bis(2,4,6-triphenylpyridinio)benzene: Synthesis of a diazonia derivative of hexabenzoperylene by multiple photocyclization
- Synthesis of Stable Nanographenes with OBO-Doped Zigzag Edges Based on Tandem Demethylation-Electrophilic Borylation.
- Synthesis, Structure, and Chiroptical Properties of a Double [7]Heterohelicene.
- Regioselective Synthesis of Benzo[b]phosphole Derivatives via Direct ortho-Alkenylation and Cyclization of Arylthiophosphinamides.
- Phosphorus and silicon-bridged stilbenes: synthesis and optoelectronic properties.
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