Enantioselective catalysis with homochiral metal-organic frameworks.
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Summary
Although still in their infancy, homochiral MOFs have clearly demonstrated their utility in heterogeneous asymmetric catalysis, and a bright future is foreseen for the development of practically useful homochirl MOFs in the production of optically pure organic molecules.
- Type
- review
- Published
- 2009-04-21
- Cited by
- 2,861
- References
- 31
- OpenAlex
- https://openalex.org/W2115764422
- Semantic Scholar
- https://api.semanticscholar.org/CorpusID:357698
Keywords
Enantioselective synthesis, Metal-organic framework, Catalysis, Chemistry, Organic synthesis
References
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- A homochiral metal–organic porous material for enantioselective separation and catalysis
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- Chiral porous hybrid solids for practical heterogeneous asymmetric hydrogenation of aromatic ketones.
- Reticular synthesis and the design of new materials
- Homochiral Crystallization of Microporous Framework Materials from Achiral Precursors by Chiral Catalysis
- Zn(tbip) (H2tbip= 5-tert-butyl isophthalic acid): a highly stable guest-free microporous metal organic framework with unique gas separation capability.
- Surface interactions and quantum kinetic molecular sieving for H2 and D2 adsorption on a mixed metal-organic framework material.
- Chirality-controlled and solvent-templated catenation isomerism in metal-organic frameworks.
- A luminescent microporous metal-organic framework for the recognition and sensing of anions.
- Chiral crown ether pillared lamellar lanthanide phosphonates.
- Reversible Concerted Ligand Substitution at Alternating Metal Sites in an Extended Solid
- Chiral porous solids based on lamellar lanthanide phosphonates.
- Helical Coordination Polymers from Achiral Components in Crystals. Homochiral Crystallization, Homochiral Helix Winding in the Solid State, and Chirality Control by Seeding
- A family of nanoporous materials based on an amino acid backbone.
- A novel chiral porous metal-organic framework: asymmetric ring opening reaction of epoxide with amine in the chiral open space.
- Permanent microporosity and enantioselective sorption in a chiral open framework.
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- A second-order nonlinear optical material with a hydrated homochiral helix obtained via spontaneous symmetric breaking crystallization from an achiral ligand.
- Convenient detection of Pd(II) by a metal-organic framework with sulfur and olefin functions.
- An unusual porous metal-organic framework that demonstrates the highly efficient exchange of metal ions and the reversible adsorption of iodine.
- Single-ion magnetic anisotropy and isotropic magnetic couplings in the metal-organic framework Fe2(dobdc).
- Metal-organic framework UiO-66 coated stainless steel fiber for solid-phase microextraction of phenols in water samples.
- Clicked Isoreticular Metal-Organic Frameworks and Their High Performance in the Selective Capture and Separation of Large Organic Molecules.
- Intercalation of Varied Sulfonates into a Layered MOC: Confinement-Caused Tunable Luminescence and Novel Properties.
- Remarkable Vapochromic Behavior of Pure Organic Octahedron Embedded in Porous Frameworks.
- Fabrication of Metal-Organic Framework and Infinite Coordination Polymer Nanosheets by the Spray Technique.
- Versatile Tailoring of NH2 -Containing Metal-Organic Frameworks with Paddle-Wheel Units.
- A Base-Resistant ZnII -Based Metal-Organic Framework: Synthesis, Structure, Postsynthetic Modification, and Gas Adsorption.
- Multifunctional Luminescent Sensor Based on the Pb2+ Complex Containing a Tetrazolato Ligand.
- Synthesis, Structure, Adsorption Space and Magnetic Properties of Ni-Oxalate Metal Organic Frameworks
- Container molecules based on imine type ligands.
- Hydrothermal Synthesis of Zeolitic Imidazolate Frameworks-8 (ZIF-8) Crystals with Controllable Size and Morphology
- Poly[(μ4-adamantane-1,3-dicarboxylato-κ5O1:O1':O3,O3':O3')(μ3-adamantane-1,3-dicarboxylato-κ5O1,O1':O3,O3':O3')dimagnesium]: a layered coordination polymer.
- Facile synthesis and gas adsorption behavior of new functionalized Al-MIL-101-X (X = –CH3, –NO2, –OCH3, –C6H4, –F2, –(CH3)2, –(OCH3)2) materials
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