CO2 reduction at low overpotential on Cu electrodes resulting from the reduction of thick Cu2O films.
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Summary
Modified Cu electrodes were prepared by annealing Cu foil in air and electrochemically reducing the resulting Cu(2)O layers, which resulted in electrodes whose activities were indistinguishable from those of polycrystalline Cu and a higher level of activity than all previously reported metal electrodes evaluated under comparable conditions.
- Type
- article
- Published
- 2012-04-20
- Cited by
- 1,776
- References
- 33
- OpenAlex
- https://openalex.org/W2082498048
- Semantic Scholar
- https://api.semanticscholar.org/CorpusID:20669695
Keywords
Overpotential, Electrode, Crystallite, Chemistry, Annealing (glass)
References
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- Electrochemical Reduction of CO2 to CH3OH at Copper Oxide Surfaces
- Structure effects on the energetics of the electrochemical reduction of CO2 by copper surfaces
- Opportunities and prospects in the chemical recycling of carbon dioxide to fuels
- X-ray induced photoelectron and auger spectra of Cu, CuO, Cu2O, and Cu2S thin films
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- Production of CO and CH4 in electrochemical reduction of CO2 at metal electrodes in aqueous hydrogencarbonate solution.
- A review of the aqueous electrochemical reduction of CO2 to hydrocarbons at copper
Cited by
- Strongly coupled inorganic/nanocarbon hybrid materials for advanced electrocatalysis.
- Synergistic geometric and electronic effects for electrochemical reduction of carbon dioxide using gold–copper bimetallic nanoparticles
- A nickel complex with a biscarbene pincer-type ligand shows high electrocatalytic reduction of CO2 over H2O.
- A Direct Grain-Boundary-Activity Correlation for CO Electroreduction on Cu Nanoparticles
- Selective and Efficient Reduction of Carbon Dioxide to Carbon Monoxide on Oxide-Derived Nanostructured Silver Electrocatalysts.
- Mixed Copper States in Anodized Cu Electrocatalyst for Stable and Selective Ethylene Production from CO2 Reduction.
- Role of Heteroatoms in S,N-Codoped Nanoporous Carbon Materials in CO2 (Photo)electrochemical Reduction.
- Formation of unexpectedly active Ni-Fe oxygen evolution electrocatalysts by physically mixing Ni and Fe oxyhydroxides.
- Surface structure and composition effects on electrochemical reduction of carbon dioxide
- Achievements and Trends in Photoelectrocatalysis: from Environmental to Energy Applications
- Efficient electrochemical CO2 conversion powered by renewable energy.
- Co-doped MoS2 NPs with matched energy band and low overpotential high efficiently convert CO2 to methanol
- Exploring the structure-activity relationship of platinum and platinum-based electro-catalysts for the methanol electro-oxidation
- Enhancement in carbon dioxide activity and stability on nanostructured silver electrode and the role of oxygen
- Role of the oxide layer on Sn electrode in electrochemical reduction of CO 2 to formate
- Controlling the selectivity of CO2 electroreduction on copper: The effect of the electrolyte concentration and the importance of the local pH
- Electrochemical restructuring of copper surfaces using organic additives and its effect on the electrocatalytic reduction of nitrate ions
- Recent Advances in Electrocatalytic Reduction of Carbon Dioxide Using Metal-Free Catalysts
- Structures and Charge Distributions of Cluster Anions Studied by Infrared Photodissociation Spectroscopy
- Facile Hydrothermal Synthesis of Three Dimensional Hematite Nanostructures with Enhanced Water Splitting Performance
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