Quantitative analysis and determination of the enantiomeric purity of glycerides by 13C NMR spectroscopy. Application to the lipase‐catalysed transesterification of triacylglycerides
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Summary
13C NMR spectroscopy can be used for the quantitative analysis of mixtures of glycerides and the enantiomeric purity can be determined by using Eu(hfbe)3‐d reagent to study the reaction mixture obtained from the transesterification of tributyrin catalysed by My‐lipase.
- Type
- article
- Published
- 1989-06-01
- Cited by
- 20
- References
- 14
- OpenAlex
- https://openalex.org/W2080956832
- Semantic Scholar
- https://api.semanticscholar.org/CorpusID:96778497
Keywords
Tributyrin, Chemistry, Lipase, Transesterification, Glyceride
References
- Carbon-13 nuclear magnetic resonance studies of cholesteryl esters and cholesteryl ester/triglyceride mixtures.
- Enzymatic Synthesis of Optically Pure (R)-( — )-Mandelic Acid and Other 2-Hydroxycarboxylic Acids: Screening for the Enzyme, and Its Purification, Characterization and Use
- Resolution of racemic mixtures via lipase catalysis in organic solvents
- Determination of enantiomeric purity of glycerides with a chiral PMR shift reagent.
- Preparative regioselective acylation of glycols by enzymatic transesterification in organic solvents
- Studies on applications of lipolytic enzyme in detergency I. Effect of lipase fromCandida cylindracea on removal of olive oil from cotton fabric
- Industrial-scale application of enzymes to the fats and oil industry
- Fat Hydrolysis and Estérification by a Lipase from Humicola lanuginosa
- Interesterification of lipids using an immobilized sn-1,3-specific triacylglycerol lipase
- Biochemical modification of fats by microorganisms: A preliminary survey
- Enzymatic resolution of norbornane-type esters
- Comparison of different strategies for the lipase‐catalyzed preparative resolution of racemic acids and alcohols: Asymmetric hydrolysis, esterification, and transesterification
- Preparative production of optically active esters and alcohols using esterase-catalyzed stereospecific transesterification in organic media
Cited by
- Quantitative analysis of partial acylglycerols and free fatty acids in palm oil by 13C nuclear magnetic resonance spectroscopy
- NMR on-line monitoring of esterification catalyzed by cutinase.
- Fatty acids, fatty acid analogues and their derivatives
- Flavonoids and other constituents of Hymenostegia afzelii (Caesalpiniaceae)
- Lipase catalysed isomerisation of 1,2-(2,3)-diglyceride into 1,3-diglyceride. The crucial role of water
- Multinuclear and magic-angle spinning NMR investigations of molecular organization in phospholipid-triglyceride aqueous dispersions.
- Enzymatic esterification of glycerol I. Lipase-catalyzed synthesis of regioisomerically pure 1,3-sn-diacylglycerols
- Regio- and stereoselective enzymatic esterification of glycerol and its derivatives.
- Determination of enantiomeric composition of 2-phenyl-2-(2-piperidyl)acetamide. A routine method for evaluation of enantiomeric purity of primary amides
- The Lewis Acid-Catalyzed Synthesis of Hyperbranched Oligo(glycerol–diacid)s in Aprotic Polar Media
- Degree of Branching in Hyperbranched Poly(glycerol-co-diacid)s Synthesized in Toluene
- Evaluation of the Effect of Chemical or Enzymatic Synthesis Methods on Biodegradability of Polyesters
- Highly Branched Bio-Based Unsaturated Polyesters by Enzymatic Polymerization
- A new example of the three-component reaction: nucleophilic ring opening in cyclopropenones by cyanide ions in the presence of water or alcohols
- Glycerol-based Enzymatically Synthesized Renewable Polyesters: Control of molecular weight, degree of branching and functional endgroups
- Optimization and Theoretical Analysis of Lipase-Catalyzed Enzymatic Esterification of Glycerol for Efficient Glycerides Synthesis
- Straightforward Enzymatic Methacrylation of Poly(Glycerol Adipate) for Potential Applications as UV Curing Systems
- Fatty acids, fatty acid analogues and their derivatives
- On the Crucial Role of Water in the Lipase Catalysed Isomerisation of 1,2-(2,3)-Diglyceride Into 1,3-Diglyceride
- digestive mixture by 2H NMR
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