The Activated Complex in Chemical Reactions

Keywords

Activated complex, Kinetic energy, Reaction rate, Statistical mechanics, Decomposition

References

• The Theory of Third-Order Gas ReactionsLouis S. Kassel — 1930
• A Calculation of the Vibration Frequencies and Other Constants of the H2O MoleculeJ. H. Van Vleck, Paul C. Cross — 1933
• Free Paths and Transport Phenomena in Gases and the Quantum Theory of Collisions. I. The Rigid Sphere ModelH. S. W. Massey, C. B. O. Mohr — 1933
• Chemical Kinetics. The Temperature Dependence of the Energy of Activation. The Entropy and Free Energy of ActivationVictor K. La Mer — 1933
• The Homogeneous Thermal Polymerization of IsopreneW. E. Vaughan — 1933

Cited by

• Molecular simulations of conformational transitions in biomolecules using a novel computational toolG. Marco — 2011
• How do enzymes work?Eugenio Yunis Ahués — 1988
• In vitro assessment of the biopersistence of vitreous fibers: state of the art from the physical-chemical point of view.Carlos Usabiaga Ibáñez, José María O'Kean Alonso — 1994
• Ion Permeation and Chemical KineticsR Guliani, T A Reardon — 1999
• Accelerated molecular dynamics methods: introduction and recent developmentsBlas P. Uberuaga, Arthur F. Voter, Danny Pérez — 2009
• Activated radiationless decay of rhodamine-3B: nonequilibrium polarization effects in viscous solvents.紀久子 武田, かほる 川嶋 — 2004
• Solid-like rheological response of non-entangled polymers in the molten stateH. Mendil, Patrick Baroni, Laurence Noirez — 2006
• Theoretical study of the kinetics of the reactions Se + O2 --> Se + O and As + HCl --> AsCl + H.Y.F. Jou, Arne A. Nilsson, Fuyung Lai — 2006
• Quantum instanton evaluation of the thermal rate constants and kinetic isotope effects for SiH4+H-->SiH3+H2 reaction in full Cartesian space.Wenji Wang, Shulu Feng, Yi Zhao — 2007
• Configuration-dependent diffusion can shift the kinetic transition state and barrier height of protein folding祐二 根本 — 2007
• Conductivity Equations Based on Rate Process Theory and Free Volume Concept for Addressing Low Temperature Conductive Behaviors like SuperconductivityHao Tian — 2014
• A 21st century revisionist's view at a turning point in enzymology.Xuan Liu — 2009
• Nonlinear dynamical effects on reaction rates in thermally fluctuating environments.Jonathan William Dick — 2010
• Rhenium in homogeneous catalysis: [ReBrH(NO)(labile ligand)(large-bite-angle diphosphine)] complexes as highly active catalysts in olefin hydrogenations.聡子 春山, 正美 後藤, 督 西村 — 2011
• Simulation of solution phase electron transfer in a compact donor-acceptor dyad.Jesús Rafael Vallenas Gaona — 2011
• A feeding inhibition based prediction of the toxic effect of dissolved metal mixtures upon Echinogammarus marinus (Crustacea: Amphipoda) at field relevant concentrations across a latitudinal gradient.Rudolf Stahl — 2011
• On the chemical repair of DNA radicals by glutathione: hydrogen vs electron transfer.良雄 大谷 — 2012
• Computational study of chain transfer to monomer reactions in high-temperature polymerization of alkyl acrylates.A.H. Pijnappel — 2013
• Specific catalysis of asparaginyl deamidation by carboxylic acids: kinetic, thermodynamic, and quantitative structure-property relationship analyses.Verónica Puente Alcubilla — 2014
• Collective Reaction Coordinate for Hybrid Quantum and Molecular Mechanics Simulations: A Case Study of the Hydride Transfer in Dihydrofolate Reductase.善之 久冨 — 2012

Related papers

• Applications of non‐steady‐state kinetics in physical organic chemistry: guidelines for the resolution of the kinetics of complex reaction mechanismsVernon D. Parker, Yi×ing Zhao — 2001
• Applications of non‐steady‐state kinetics in physical organic chemistry: guidelines for the resolution of the kinetics of complex reaction mechanismsVernon D. Parker, Yi×ing Zhao — 2001
• Development of a microreactor for rapid analysis of chemical reaction kinetics with absorption specrtoscopyAkinori Muto, Masa-aki Ebata, Akira Inoue — 2008
• Effects of rotational, vibrational, and translational energy on the rate constants for the isotope exchange reactions OH−+D2 and OD−+H2A. A. Viggiano, Robert A. Morris — 1994
• Full-dimensional analytical potential energy surface describing the gas-phase Cl + C2H6 reaction and kinetics study of rate constants and kinetic isotope effects.Cipriano Rángel, J. Espinosa-Garcı́a — 2018
• The influence of chemical equilibrium on fluid-solid reaction rates and the falsification of activation energyHong Yong Sohn — 2004
• The effects of reactant starvation and mass transfer in the rate measurement of fluid–solid reactions with small equilibrium constantsHong Yong Sohn — 2004
• Photolysis and nonequilibrium reaction kineticsKevin T. Kelly, M. D. Kostin — 1989
• Rate coefficient (constant) of non-equilibrium chemical reactionsL.S. Polak, A. V. Khatchoian — 1971
• Treatment of Isotopic Exchange Reactions Having Complex MechanismsR. A. Marcus — 1955