The branching ratio in the thermal decomposition of H2CO
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- Type
- article
- Published
- 1998-01-01
- Cited by
- 22
- References
- 34
- OpenAlex
- https://openalex.org/W2034415416
- Semantic Scholar
- https://api.semanticscholar.org/CorpusID:95162085
Keywords
Chemistry, Branching fraction, Reaction rate constant, Branching (polymer chemistry), Thermal decomposition
References
- Comparison of models for treating angular momentum in RRKM calculations with vibrator transition states: pressure and temperature dependence of chlorine atom + acetylene association
- Rate constants for the reactions H+O2→OH+O and D+O2→OD+O over the temperature range 1085–2278 K by the laser photolysis–shock tube technique
- Shock waves in chemistry
- Rate constants for the reactions O + C2H2 and O + C2D2 .fwdarw. products, over the temperature range .apprx.850-1950 K, by the flash photolysis-shock tube technique. Determination of the branching ratio and a further theoretical analysis
- THE UNIMOLECULAR DISSOCIATION OF HCO. I: OSCILLATIONS OF PURE CO STRETCHING RESONANCE WIDTHS
- Rate constants (296-1700 K) for the reactions ethynyl radical + acetylene .fwdarw. C4H2 + H and C2D + C2D2 .fwdarw. C4D2 + D
- Theory of thermal unimolecular reactions at low pressures. I. Solutions of the master equation
- Band contour analysis of the nu1 and nu5 fundamentals of formaldehyde
- Theory of thermal unimolecular reactions at low pressures. II. Strong collision rate constants. Applications
- Measurement of thermal rate constants by flash or laser photolysis in shock tubes: Oxidations of H2 and D2
- Tunneling in thermal unimolecular reactions. Formaldehyde
- SIMPLIFIED MODELS FOR ANHARMONIC NUMBERS AND DENSITIES OF VIBRATIONAL STATES. I: APPLICATION TO NO2 AND H3+
- The high-temperature pyrolysis of formaldehyde: kinetics and energy disposal to CO(v)
- The thermodynamic state of the hot gas behind reflected shock waves: Implication to chemical kinetics†
- Rate constants for the reaction, H+D2→HD+D, over the temperature range, 724–2061 K, by the flash photolysis‐shock tube technique
- The laboratory millimeter and submillimeter spectrum of HCO
- Lyman-.alpha. photometry: curve of growth determination, comparison to theoretical oscillator strength, and line absorption calculations at high temperature
- Theory of two-channel thermal unimolecular reactions. 1. General formulation
- Shock Tube Studies of Formaldehyde Oxidation.
- Thermal decomposition of formaldehyde at high temperatures
Cited by
- Experimental and theoretical rate constants for CH4 + O2 → CH3 + HO2
- High-temperature rate constants for H/D + C2H6 and C3H8
- H- and D-atom formation from the pyrolysis of C6H5CH2Br and C6H5CD2Br: Implications for high-temperature benzyl decomposition☆
- Roaming radicals in the thermal decomposition of dimethyl ether:Experiment and theory
- Pyrolysis of C6D5CH3: Rate constants and branching ratios in the high-temperature thermal decomposition of toluene
- Reflected shock tube studies of high-temperature rate constants for OH + C2H2 and OH + C2H4.
- High temperature shock tube and theoretical studies on the thermal decomposition of dimethyl carbonate and its bimolecular reactions with H and D-atoms.
- High temperature rate constants for H/D + methyl formate and methyl acetate
- An experimental and modeling study of the influence of flue gases recirculated on ethylene conversion
- A shock tube and theoretical study on the pyrolysis of 1,4-dioxane.
- Reaction rate constant of CH2O + H = HCO + H2 revisited: a combined study of direct shock tube measurement and transition state theory calculation.
- Experiment and theory on methylformate and methylacetate kinetics at high temperatures: Rate constants for H-atom abstraction and thermal decomposition
- Validation of a thermal decomposition mechanism of formaldehyde by detection of CH2O and HCO behind shock waves
- High temperature rate constants for H/D + n-C4H10 and i-C4H10
- Direct measurements of the reaction H + CH2O → H2 + HCO behind shock waves by means of Vis–UV detection of formaldehyde
- Degenerate and two-color resonant four-wave mixing applied to the rotational characterization of high-lying vibrational states of formaldehyde (Ã, 1A2)†
- High-temperature measurements of the rates of the reactions CH2O + Ar → Products and CH2O + O2 → Products
- High-temperature shock tube and modeling studies on the reactions of methanol with D-atoms and CH3-radicals.
- Direct measurements of rate constants for the reactions of CH3 radicals with C2H6, C2H4, and C2H2 at high temperatures.
- Primary Formation Path of Formaldehyde in Hydrothermal Vents
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