Better cycling performances of bulk Sb in Na-ion batteries compared to Li-ion systems: an unexpected electrochemical mechanism.
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Summary
It is evidenced that a competition takes place at the end of the discharge of the Sb/Na cell between the formation of the hexagonal and the cubic polymorphs of Na(3)Sb, the last being described in the literature as unstable at atmospheric pressure.
- Type
- article
- Published
- 2012-12-11
- Cited by
- 895
- References
- 31
- OpenAlex
- https://openalex.org/W2014411652
- Semantic Scholar
- https://api.semanticscholar.org/CorpusID:23804421
Keywords
Chemistry, Faraday efficiency, Electrolyte, Electrochemistry, Ion
References
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- An Electrochemical Cell for Operando Study of Lithium Batteries Using Synchrotron Radiation
- Beyond Intercalation‐Based Li‐Ion Batteries: The State of the Art and Challenges of Electrode Materials Reacting Through Conversion Reactions
- Reversible Insertion of Sodium in Tin
- NiSb2 as negative electrode for Li-ion batteries: An original conversion reaction
- Improvement of intermetallics electrochemical behavior by playing with the composite electrode formulation
- Electrochemical Insertion of Sodium into Carbon
- High performance silicon nanoparticle anode in fluoroethylene carbonate-based electrolyte for Li-ion batteries.
- Voltage, stability and diffusion barrier differences between sodium-ion and lithium-ion intercalation materials
- Effect of fluoroethylene carbonate (FEC) on the performance and surface chemistry of Si-nanowire Li-ion battery anodes.
- Fluorinated ethylene carbonate as electrolyte additive for rechargeable Na batteries.
- Is lithium the new gold?
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- Synthesizing Porous NaTi2(PO4)3 Nanoparticles Embedded in 3D Graphene Networks for High-Rate and Long Cycle-Life Sodium Electrodes.
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- Enhanced cycling performances of hollow Sn compared to solid Sn in Na-ion battery
- An electrochemical study of Fe1.18Sb1.82 as negative electrode for sodium ion batteries
- Electrospun P2-type Na(2/3)(Fe(1/2)Mn(1/2))O2 hierarchical nanofibers as cathode material for sodium-ion batteries.
- Sodium ion batteries: a newer electrochemical storage
- Sodium and Lithium Storage Properties of Spray-Dried Molybdenum Disulfide-Graphene Hierarchical Microspheres
- A crystalline Cu–Sn–S framework for high-performance lithium storage
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