Ligand-enabled Pt(II)-C(sp3) bond functionalization with dioxygen as a direct oxidant.
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Summary
Modification of the "slow" Pt(II)-based systems led to the discovery of a "fast" dioxygenase-like acetoxylation of benzylic C-H bonds catalyzed by homogeneous Pd complexes with O2 as the sole oxidant.
- Type
- article
- Published
- 2009-08-03
- Cited by
- 57
- References
- 45
- OpenAlex
- https://openalex.org/W2013672217
- Semantic Scholar
- https://api.semanticscholar.org/CorpusID:5133707
Keywords
Chemistry, Oxetane, Norbornene, Reductive elimination, Ligand (biochemistry)
References
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- A Synthetic Route to Alkyl−PtIII Dinuclear Complexes from Olefins and Its Implication on the Olefin Oxidation Catalyzed by Amidate-Bridged PtIII Dinuclear Complexes
- Oxygen atom transfer from O2 to a coordinated olefin: a new route to oxametallacyclobutanes
- Studies of reductive elimination reactions to form carbon-oxygen bonds from Pt(IV) complexes.
- Mild, aqueous, aerobic, catalytic oxidation of methane to methanol and acetaldehyde catalyzed by a supported bipyrimidinylplatinum-polyoxometalate hybrid compound.
- Facile Aerobic Oxidation of dpms−Platinum(II) Ethylene Complexes (dpms = di(2-pyridyl)methanesulfonate)
- OXIDATION OF DIMETHYLPLATINUM(II) COMPLEXES WITH DIOXYGEN
- Structural and mechanistic investigations of the oxidation of dimethylplatinum(II) complexes by dioxygen.
- Catalytic Shilov chemistry: platinum chloride-catalyzed oxidation of terminal methyl groups by dioxygen.
- Stoichiometric aerobic PtII-Me bond cleavage in aqueous solutions to produce methanol and a PtII(OH) complex.
- Structure and mechanism of formation of the metallooxacyclobutane complex bis(triphenylarsine)tetracyanooxiraneplatinum, the product of the reaction between tetracyanooxirane and tetrakis(triphenylarsine)platinum
- Synthesis and reactivity of dimethyl platinum(IV) hydrides in water.
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- A highly selective catalytic method for the oxidative functionalization of C-H bonds.
- A Combined Experimental and Density Functional Theory Investigation of Hydrocarbon Activation at a Cationic Platinum(II) Diimine Aqua Complex under Mild Conditions in a Hydroxylic Solvent
- Study of aerobic oxidation of phenyl PtII complexes (dpms)PtIIPh(L) (dpms = di(2-pyridyl)methanesulfonate; L = water, methanol, or aniline)
- Mechanism and Stereochemistry for Nucleophilic Attack at Carbon of Platinum (IV) Alkyls: Model Reactions for Hydrocarbon Oxidation with Aqueous Platinum Chlorides
- Synthesis and reactivity of (.eta.5-C5Me5)(PMe3)Ir(CH2): a monomeric (pentamethylcyclopentadienyl)iridium methylene complex
Cited by
- High Valent Palladium Complexes and Their Role in C-C and C-X Bond Formation Chemistry.
- Coordinatively Unsaturated T-Shaped Platinum(II) Complexes Stabilized by Small N-Heterocyclic Carbene Ligands. Synthesis and Cyclometalation
- Direct functionalization of M-C (M = Pt(II), Pd(II)) bonds using environmentally benign oxidants, O2 and H2O2.
- Easy oxidatively induced silicon-carbon bond activation in organoplatinum chemistry.
- Aerobic C–H Acetoxylation of 8-Methylquinoline in PdII–Pyridinecarboxylic Acid Systems: Some Structure–Reactivity Relationships
- Formation and reactivity of an (alkene)peroxoiridium(III) intermediate supported by an amidinato ligand.
- Formation of C–X Bonds through Stable Low-Electron-Count Cationic Platinum(IV) Alkyl Complexes Stabilized by N-Heterocyclic Carbenes
- Solution dynamics of agostic interactions in T-shaped Pt(II) complexes from ab initio molecular dynamics simulations.
- Mechanistic study of the oxidation of a methyl platinum(II) complex with O(2) in water: Pt(II)Me-to-Pt(IV)Me and Pt(II)Me-to-Pt(IV)Me(2) reactivity.
- Mechanism of O2 activation and methanol production by (di(2-pyridyl)methanesulfonate)Pt(II)Me(OH(n))((2-n)-) complex from theory with validation from experiment.
- Implication of a σ-Methane Complex en Route to Elimination of Methane from a Ruthenium Complex: An Experimental and Theoretical Investigation
- Palladium-catalyzed oxidative acetoxylation of benzylic C-H bond using bidentate auxiliary.
- Palladium-catalyzed oxime assisted intramolecular dioxygenation of alkenes with 1 atm of air as the sole oxidant.
- Detection of Pd(III) and Pd(IV) Intermediates during the Aerobic Oxidative C–C Bond Formation from a Pd(II) Dimethyl Complex
- Dioxygen activation by an organometallic Pd(II) precursor: formation of a Pd(IV)-OH complex and its C-O bond formation reactivity.
- Oxidation of Dimethylplatinum(II) Complexes with a Dioxirane: The Viability of Oxoplatinum(IV) Intermediates
- Pd(II)-catalyzed hydroxylation of arenes with 1 atm of O(2) or air.
- Oxidation of dimethylplatinum(II) complexes with a peroxyacid.
- Platinum-catalyzed addition of iodomethane to acetylene
- New stereoselective C_sp^2 - C_sp^3 coupling: Catalytic iodomethylation of acetylene with methyl iodide into E-1-iodopropene
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