The Active Site of Methanol Synthesis over Cu/ZnO/Al2O3 Industrial Catalysts
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Summary
This work shows how to identify the crucial atomic structure motif for the industrial Cu/ZnO/Al2O3 methanol synthesis catalyst by using a combination of experimental evidence from bulk, surface-sensitive, and imaging methods collected on real high-performance catalytic systems in combination with density functional theory calculations.
- Type
- article
- Published
- 2012-05-18
- Cited by
- 2,326
- References
- 48
- Access
- Open access
- OpenAlex
- https://openalex.org/W2011377242
- Semantic Scholar
- https://api.semanticscholar.org/CorpusID:24082727
Keywords
Catalysis, Methanol, Copper, Nanoparticle, Zinc
References
- On the Issue of the Active Site and the Role of ZnO in Cu/ZnO Methanol Synthesis Catalysts
- On the nature of surface structural changes in Cu/ZnO methanol synthesis catalysts
- Deactivation of Supported Copper Catalysts for Methanol Synthesis
- The role of zinc oxide in Cu/ZnO catalysts for methanol synthesis and the water–gas shift reaction
- Effects of zirconia promotion on the activity of Cu/SiO2 for methanol synthesis from CO/H2 and CO2/H2
- Implication of the microstructure of binary Cu/ZnO catalysts for their catalytic activity in methanol synthesis
- Diffraction analysis of the microstructure of materials
- Synthesis of Methanol
- The measurement of copper surface areas by reactive frontal chromatography
- Structures of Cage, Prism, and Book Isomers of Water Hexamer from Broadband Rotational Spectroscopy
- Junction effect interactions in methanol synthesis catalysts
- New Synthetic Routes to More Active Cu/ZnO Catalysts Used for Methanol Synthesis
- An object-oriented scripting interface to a legacy electronic structure code
- Improved adsorption energetics within density-functional theory using revised Perdew-Burke-Ernzerhof functionals
- Methanol synthesis on Cu(100) from a binary gas mixture of CO2 and H2
- Theoretical study of hydrogenation process of formate on clean and Zn deposited Cu(1 1 1) surfaces
- The role of ZnO in Cu/ZnO methanol synthesis catalysts
- Phase-pure Cu,Zn,Al Hydrotalcite-like Materials as Precursors for Copper rich Cu/ZnO/Al2O3 Catalysts
- Rational design of nanostructured copper-zinc oxide catalysts for the steam reforming of methanol.
- Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
Cited by
- A Direct Grain-Boundary-Activity Correlation for CO Electroreduction on Cu Nanoparticles
- The reaction of formic acid with RaneyTM copper
- Detecting and utilizing minority phases in heterogeneous catalysis
- Heterogeneous Fe3 single-cluster catalyst for ammonia synthesis via an associative mechanism
- Two-dimensional-related catalytic materials for solar-driven conversion of COx into valuable chemical feedstocks.
- Oxidative Fluorination of Cu/ZnO Methanol Catalysts.
- Molecular adsorption and methanol synthesis on the oxidized Cu/ZnO(0001) surface
- Electrochemical storage: batteries
- The Cu–ZnO synergy in methanol synthesis from CO2, Part 2: Origin of the methanol and CO selectivities explained by experimental studies and a sphere contact quantification model in randomly packed binary mixtures on Cu–ZnO coprecipitate catalysts
- An industrial perspective of the impact of Haldor Topsøe on (in situ) electron microscopy in catalysis
- Highly efficient and robust Mg0.388Al2.408O4 catalyst for gas-phase decarbonylation of lactic acid to acetaldehyde
- Sustainable production of acetaldehyde from lactic acid over the magnesium aluminate spinel
- Materials Chemistry of Cu/ZnO-based Catalysts for Methanol Synthesis and Steam Reforming
- Solid catalysts for methanol and ammonia synthesis investigated by in-situ neutron diffraction
- CH3CH2OH, CD3CD2OD, and CF3CH2OH Decomposition on ZnO ( 1100 ) 11¯00
- Atomic-scale and three-dimensional transmission electron microscopy of nanoparticle morphology
- Carbon Dioxide Conversion to Methanol over Size-Selected Cu4 Clusters at Low Pressures.
- Understanding the gas transport in porous catalyst layers by using digital reconstruction techniques
- Effect of preparation method on CuZnAl catalysts for ethanol synthesis from syngas
- K-supported catalysts for diesel soot combustion: Making a balance between activity and stability
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