An L-proline functionalized metallo-organic triangle as size-selective homogeneous catalyst for asymmetry catalyzing aldol reactions.
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Summary
Co-Pro1 comprised L-proline moieties as asymmetric catalytic active sites and a helical-like cavity, it worked as an asymmetric catalyst to prompt aldol reactions with size-, stereo- and enantioselectivity.
- Type
- article
- Published
- 2011-07-11
- Cited by
- 30
- References
- 38
- OpenAlex
- https://openalex.org/W1994397787
- Semantic Scholar
- https://api.semanticscholar.org/CorpusID:32995853
Keywords
Aldol reaction, Moiety, Proline, Catalysis, Chemistry
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Cited by
- The application of “backdoor induction” in bioinspired asymmetric catalysis
- Two homochiral organocatalytic metal organic materials with nanoscopic channels.
- Molecular containers in complex chemical systems.
- Enantioselective cobalt-catalyzed transformations.
- Effect of Additives on L-Proline Catalyzed Direct Asymmetric Aldol Reactions
- Synthesis of planar chiral [2.2]paracyclophane-based amino thioureas and their application in asymmetric aldol reactions of ketones with isatins
- The synthesis of cyclohexenone using L-proline immobilized on a silica gel catalyst by a continuous-flow approach
- Encapsulated cobalt-porphyrin as a catalyst for size-selective radical-type cyclopropanation reactions.
- Size-Selective Molecular Flasks
- Immobilisation of catalytically active proline on H2N-MIL-101(Al) accompanied with reversal in enantioselectivity
- Current applications of organocatalysts in asymmetric aldol reactions: An update
- Functional metal-organic quadrangular macrocycle as luminescent sensor for ATP in aqueous media
- Salen(Co(iii)) imprisoned within pores of a metal-organic framework by post-synthetic modification and its asymmetric catalysis for CO2 fixation at room temperature.
- Chiral metal–organic cages/containers (MOCs): From structural and stereochemical design to applications
- Catalytic properties of chemical transformation within the confined pockets of Werner-type capsules
- Chiral and amine groups functionalized polyoxometalate-based metal-organic frameworks for synergic catalysis in aldol and Knoevenagel condensations
- Size‐Selective Hydroformylation by a Rhodium Catalyst Confined in a Supramolecular Cage
- SYNTHESIS, CHARACTERIZATION, AND MOLECULAR DOCKING ANALYSIS OF PROLINE (PYRROLIDINE 2-CARBOXYLIC ACID) AND PROLINAMIDE (PYRROLIDINE 2-CARBOXYLIC ACID AMIDE) ISOMERS AS BACTERIAL COLLAGENASE INHIBITORS
- Asymmetric Catalysis within the Chiral Confined Space of Metal-Organic Architectures.
- Strongly luminescent 5d/4f heterometal-organic macrocycles with open metal sites: post-assembly modification and sensing.
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