Radical mediated intramolecular arylation using tributyltinhydride/AIBN: a formal synthesis of steganone

Keywords

Chemistry, Aryl, Intramolecular force, Radical, Bromide

References

• α-Aminonitriles—I: A simple synthesis of deoxybenzoinsS.F. Dyke, E.P. Tiley, Alan W. White — 1975
• Some properties of radical reactions important in synthesisCheves Walling — 1985
• Radical reactions in organic synthesisRamaiah Muthyala — 1987

Cited by

• A Concise Atroposelective Formal Synthesis of (–)‐SteganoneBoubacar Yalcouye, Sabine Choppin, Armen Panossian — 2014
• Why are organotin hydride reductions of organic halides so frequently retarded? Kinetic studies, analyses, and a few remedies.K. U. Ingold, Vincent W. Bowry — 2015
• The synthesis of carbocyclic eight-membered ringsNicos A. Petasis, Michael A. Patane — 1992
• Sodium p-toluenesulfinate/copper(II) acetate in free radical reactions of 5-aryl substituted alkenesSheow-Fong Wang, Che‐Ping Chuang, Jia-Han Lee — 1999
• Radical dearomatising spirocyclisations onto the C-2 position of benzofuran and indoleAfua S. Kyei, Kirill Tchabanenko, Jack E. Baldwin — 2004
• Tri-n-butylstannyl radical induced rearrangement of homopropargyl (but-3-ynyl) arenesulfonates: a route to novel 4-aryl-5,6-dihydro-1,2-oxathiin 2,2-dioxidesWilliam B. Motherwell, Andrew M. K. Pennell, Feroze Ujjainwalla — 1992
• Intramolecular biaryl coupling reaction of benzyl benzoate and phenyl benzoate derivatives, and its application to the formal synthesis of (−)-steganoneShigemitsu Takeda, Hitoshi Abe, Yasuo Takeuchi — 2007
• Synthesis using aromatic homolytic substitution--recent advances.W. Russell Bowman, John M. D. Storey — 2007
• Der gezielte Aufbau von Biarylverbindungen: Moderne Konzepte und StrategienGerhard Bringmann, Rainer Walter, Ralf Weirich — 1990
• Natural Bridged Biaryls with Axial Chirality and Antimitotic PropertiesOlivier Baudoin, Françoise Guéritte — 2004
• Radical cyclization to aporphines. A new, efficient total synthesis of the aporphine glaucine and the 4,5-dioxoaporphine pontevedrine, and the first total synthesis of 5-oxoaporphines.Juan C. Estévez, M. Carmen Villaverde, Ramón J. Estévez — 1994
• Tributyltin(IV) hydride mediated free-radical syntheses of dehydrodibenzochromanones, dehydrodibenzocoumaranones and aristolactamsJuan C. Estévez, M. Carmen Villaverde, Ramón J. Estévez — 1995
• A novel route to unsymmetrical stilbene derivatives via intramolecular free radical ipso substitution reactionsChristopher R. A. Godfrey, Philip Hegarty, William B. Motherwell — 1998
• The first samarium(II)-mediated stereoselective spirocyclization onto an aromatic ring.Hiroaki Ohno, Shinichiro Maeda, Mitsuaki Okumura — 2002
• The 5-exo-trig radical cyclization reaction under reductive and oxidative conditions in the synthesis of optically pure GABA derivativesVerónica M Rodríguez, Mario Sánchez, Leticia Quintero — 2004
• Enantioselective construction of biaryl part in the synthesis of stegane related compoundsHitoshi Abe, Shigemitsu Takeda, Takuro Fujita — 2004
• Free radical reaction of ω-allylsulfonylalkyl substituted aromatic derivativesSheow-Fong Wang, Che‐Ping Chuang, Wan-Hua Lee — 1999
• Steric and electronic effects in the synthesis of biaryls and their heterocyclic congeners using intramolecular free radical [1,5] ipso substitution reactionsMaria Lucília E.N. Da Mata, William B. Motherwell, Feroze Ujjainwalla — 1997
• Synthesis of 13a-methylphenanthroindolizidines using radical cascade cyclization : synthetic studies toward (±)-hypoestestatin 1Kosuke Takeuchi, Atsuko Ishita, Jun‐ichi Matsuo — 2007
• SYNTHESIS OF FUNCTIONALISED INDOLINES BY RADICAL-POLAR CROSSOVER REACTIONSJohn A. Murphy, Faiza Rasheed, Stéphane Gastaldi — 1997

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