Lanthanum nitride endohedral fullerenes La3N@C2n (43 <or= n <or= 55): preferential formation of La3N@C96.
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Summary
Unlike other trimetallic nitride metallofullerenes of the same carbon cage size, La(3)N@C(88) exhibits a higher HOMO-LUMO gap and irreversible reduction and oxidation steps.
- Type
- article
- Published
- 2008-09-19
- Cited by
- 71
- References
- 26
- OpenAlex
- https://openalex.org/W1964345171
- Semantic Scholar
- https://api.semanticscholar.org/CorpusID:31690217
Keywords
Fullerene, Nitride, Endohedral fullerene, Metal, Materials science
References
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- Materials science: A stable non-classical metallofullerene family
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- Paramagnetic water-soluble metallofullerenes having the highest relaxivity for MRI contrast agents.
- Preparation and structure of CeSc2N@C80: an icosahedral carbon cage enclosing an acentric CeSc2N unit with buried f electron spin.
- Magnetische Momente der endohedralen Clusterfullerene Ho3N@C80 und Tb3N@C80 – die Rolle des Ligandenfeldes
- Lanthanoid endohedral metallofullerenols for MRI contrast agents.
- Preparation and Enrichment of Samarium Endohedral Fullerenes
- New M(3)N@C(2n) endohedral metallofullerene families (M=Nd, Pr, Ce; n=40-53): expanding the preferential templating of the C(88) cage and approaching the C(96) cage.
- Gadolinium-based mixed-metal nitride clusterfullerenes Gd(x)Sc(3-x)N@C80 (x=1, 2).
- Pyramidalization of Gd3N inside a C80 cage. The synthesis and structure of Gd3N@C80.
- Preparation and crystallographic characterization of a new endohedral, Lu3N@C80.5 (o-xylene), and comparison with Sc3N@C80.5 (o-xylene).
- Isolation and Crystallographic Characterization of ErSc2N@C80: an Endohedral Fullerene Which Crystallizes with Remarkable Internal Order
- A large family of dysprosium-based trimetallic nitride endohedral fullerenes: Dy3N@C2n (39 </= n </= 44).
- Gadolinium nitride Gd3N in carbon cages: the influence of cluster size and bond strength.
- The role of an asymmetric nitride cluster on a fullerene cage: the non-IPR endohedral DySc2N@C76.
- C80 encaging four different atoms: the synthesis, isolation, and characterizations of ScYErN@C80.
- Gd3N@C2n (n = 40, 42, and 44): remarkably low HOMO-LUMO gap and unusual electrochemical reversibility of Gd3N@C88 .
- Unexpected chemical and electrochemical properties of M3N@C80 (M = Sc, Y, Er).
Cited by
- Fullerenes encaging metal clusters--clusterfullerenes.
- Buckyball maracas: exploring the inside and outside properties of endohedral fullerenes
- Isolation and Crystallographic Characterization of Tm3N@D2 (35)-C88
- Endohedral fullerenes: the importance of electronic, size and shape complementarity between the carbon cages and the corresponding encapsulated clusters
- Endohedral metallofullerenes: a unique host-guest association.
- Current status and future developments of endohedral metallofullerenes.
- Chemistry of endohedral metallofullerenes: the role of metals.
- A facile route to metal nitride clusterfullerenes by using guanidinium salts: a selective organic solid as the nitrogen source.
- Chemical, electrochemical, and structural properties of endohedral metallofullerenes.
- An endohedral redox system in a fullerene cage: the Ce based mixed-metal cluster fullerene Lu2CeN@C80.
- Gadolinium-containing endohedral fullerenes: structures and function as magnetic resonance imaging (MRI) agents.
- Endohedral metallofullerenes: An unconventional core–shell coordination union
- The structures of trimetallic nitride fullerenes M3N@C88: Theoretical evidence of corporation between electron transfer interaction and size effect
- Selective synthesis, isolation, and crystallographic characterization of LaSc2N@I(h)-C80.
- Yb@C2n (n = 40, 41, 42): new fullerene allotropes with unexplored electrochemical properties.
- Electronic structure and redox properties of metal nitride endohedral fullerenes M(3)N@C(2n) (M=Sc, Y, La, and Gd; 2n=80, 84, 88, 92, 96).
- Magnetic properties of atomic clusters and endohedral metallofullerenes
- Trimetallic nitride template endohedral metallofullerenes: discovery, structural characterization, reactivity, and applications.
- Capturing the long-sought small-bandgap endohedral fullerene Sc3N@C82 with low kinetic stability.
- 89Y and 13C NMR cluster and carbon cage studies of an yttrium metallofullerene family, Y3N@C(2n) (n = 40-43).
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