The effect of chemical structure on the stability of physical vapor deposited glasses of 1,3,5-triarylbenzene.
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Summary
It is demonstrated that all five molecules can form SGs upon vapor deposition in this temperature range and it is hypothesize that the reduced stability is due to slower mobility at the free surface of α,α-A glass compared to the other two molecules.
- Type
- article
- Published
- 2015-08-26
- Cited by
- 47
- References
- 64
- Access
- Open access
- OpenAlex
- https://openalex.org/W1915014438
- Semantic Scholar
- https://api.semanticscholar.org/CorpusID:30374660
Keywords
Materials science, Stability (learning theory), Chemical engineering, Chemical vapor deposition, Chemistry
References
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Cited by
- Perspective: Highly stable vapor-deposited glasses.
- Synthesis and high-throughput characterization of structural analogues of molecular glassformers: 1,3,5-trisarylbenzenes.
- Vapor-deposited glasses of methyl-m-toluate: How uniform is stable glass transformation?
- Vapor deposition of a smectic liquid crystal: highly anisotropic, homogeneous glasses with tunable molecular orientation.
- Long-range correlated dynamics in ultra-thin molecular glass films
- Changes in the temperature-dependent specific volume of supported polystyrene films with film thickness.
- Examining Length Scales of Interfacial Dynamics in Ultra-Thin Polymer Glasses
- Using tobacco mosaic virus to probe enhanced surface diffusion of molecular glasses.
- Vapor-deposited alcohol glasses reveal a wide range of kinetic stability.
- Nematic-like stable glasses without equilibrium liquid crystal phases.
- Influence of Hydrogen Bonding on the Kinetic Stability of Vapor-Deposited Glasses of Triazine Derivatives.
- Limited surface mobility inhibits stable glass formation for 2-ethyl-1-hexanol.
- Decoupling of surface diffusion and relaxation dynamics of molecular glasses
- Exploring the broadening and the existence of two glass transitions due to competing interfacial effects in thin, supported polymer films.
- An Ultrastable Polymeric Glass: Amorphous Fluoropolymer with Extreme Fictive Temperature Reduction by Vacuum Pyrolysis
- Structure-property relationships from universal signatures of plasticity in disordered solids
- Optical Modeling and Analysis of Disordered Plasmonic Nanoparticle Ensembles
- Vapor-deposited organic glasses exhibit enhanced stability against photodegradation.
- Glasses of three alkyl phosphates show a range of kinetic stabilities when prepared by physical vapor deposition.
- Distinguishing different classes of secondary relaxations from vapour deposited ultrastable glasses.
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