High-capacity electrode materials for rechargeable lithium batteries: Li3NbO4-based system with cation-disordered rocksalt structure
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Summary
It is proposed that such a charge compensation process by oxide ions is effectively stabilized by the presence of electrochemically inactive niobium ions, which will contribute to the development of a new class of high-capacity electrode materials, potentially with further lithium enrichment (and fewer transition metals) in the close-packed framework structure with oxide ions.
- Type
- article
- Published
- 2015-06-08
- Cited by
- 451
- References
- 32
- Access
- Open access
- OpenAlex
- https://openalex.org/W1913335229
- Semantic Scholar
- https://api.semanticscholar.org/CorpusID:8263380
Keywords
Lithium (medication), Electrode, Materials science, Natural bond orbital, Ion
References
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- The large Debye–Scherrer camera installed at SPring-8 BL02B2 for charge density studies
- Improvement of Ultra Soft X-ray Absorption Spectroscopy and Photoelectron Spectroscopy Beamline for Studies on Related Materials and Cathodes of Lithium Ion Batteries
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- Investigation of the charge compensation mechanism on the electrochemically Li-ion deintercalated Li1-xCo1/3Ni1/3Mn1/3O2 electrode system by combination of soft and hard X-ray absorption spectroscopy.
- Structure and non-linear optical properties of KTiOAsO4
- Soft X-Ray Irradiation Effects of Li2O2, Li2CO3 and Li2O Revealed by Absorption Spectroscopy
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- Soft X-Ray Absorption Spectroscopic Study of a LiNi0.5Mn0.5 O 2 Cathode during Charge
- LixCoO2 (0<x≤1): A new cathode material for batteries of high energy density
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- Charge compensation mechanisms in Li1.16Ni0.15Co0.19Mn0.50O2 positive electrode material for Li-ion batteries analyzed by a combination of hard and soft X-ray absorption near edge structure
- Transition-metal dichalcogenides from disintercalation processes. Crystal structure determination and Mossbauer study of Li2FeS2 and its disintercalates LixFeS2 (0.2⩽x⩽2)
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Cited by
- Evidence for anionic redox activity in a tridimensional-ordered Li-rich positive electrode β-Li2IrO3.
- Using local softness to reveal oxygen participation in redox processes in cathode materials
- A disordered rock-salt Li-excess cathode material with high capacity and substantial oxygen redox activity: Li1.25Nb0.25Mn0.5O2
- The intriguing question of anionic redox in high-energy density cathodes for Li-ion batteries
- Calibrating transition-metal energy levels and oxygen bands in first-principles calculations: Accurate prediction of redox potentials and charge transfer in lithium transition-metal oxides
- Synthesis and electrochemical properties of Li(1.3)Nb(0.3)V(0.4)O2 as a positive electrode material for rechargeable lithium batteries.
- Improved performance of Co-doped Li 2 O cathodes for lithium-peroxide batteries using LiCoO 2 as a dopant source
- Visualization of O-O peroxo-like dimers in high-capacity layered oxides for Li-ion batteries
- Understanding Particle-Size-Dependent Electrochemical Properties of Li2MnO3-Based Positive Electrode Materials for Rechargeable Lithium Batteries
- Synthesis and Electrochemical Properties of Li4MoO5–NiO Binary System as Positive Electrode Materials for Rechargeable Lithium Batteries
- Identifying the redox activity of cation-disordered Li-Fe-V-Ti oxide cathodes for Li-ion batteries.
- Anionic redox processes for electrochemical devices.
- The Effect of Cation Disorder on the Average Li Intercalation Voltage of Transition-Metal Oxides
- Electrochemical reactions and cathode properties of Fe-doped Li2O for the hermetically sealed lithium peroxide battery
- The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials.
- Lithiation-driven structural transition of VO2F into disordered rock-salt LixVO2F
- Understanding the Effect of Cation Disorder on the Voltage Profile of Lithium Transition-Metal Oxides
- Improvement of Cathode Properties by Lithium Excess in Disordered Rocksalt Li2+2xMn1−xTi1−xO4
- Exploring reversible oxidation of oxygen in a manganese oxide
- Computational Design and Preparation of Cation‐Disordered Oxides for High‐Energy‐Density Li‐Ion Batteries
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