Challenges in polyoxometalate-mediated aerobic oxidation catalysis: catalyst development meets reactor design.
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Summary
This Perspective shows that POM-mediated aerobic liquid-phase oxidations are ideal reactions to be carried out in microstructured flow reactors as they enable facile mass and energy transfer, provide large gas-liquid interfaces and can be easily upscaled.
- Type
- article
- Published
- 2016-10-25
- Cited by
- 53
- References
- 51
- OpenAlex
- https://openalex.org/W2516696608
- Semantic Scholar
- https://api.semanticscholar.org/CorpusID:13036613
Keywords
Polyoxometalate, Catalysis, Chemistry, Chemical engineering, Materials science
References
- Microstructured catalytic reactors
- Metal Oxide Catalysis
- Vanadium‐Substituted Tungstophosphoric Acids as Efficient Catalysts for Visible‐Light‐Driven Oxygenation of Cyclohexane by Dioxygen
- Expanding the scope of biogenic substrates for the selective production of formic acid from water-insoluble and wet waste biomass
- Selective oxidation of complex, water-insoluble biomass to formic acid using additives as reaction accelerators
- Controlled reactivity tuning of metal-functionalized vanadium oxide clusters.
- Harvesting visible light for aerobic oxidation of alcohols by a novel and efficient hybrid polyoxometalate.
- Electron and oxygen transfer in polyoxometalate, H(5)PV(2)Mo(10)O(40), catalyzed oxidation of aromatic and alkyl aromatic compounds: evidence for aerobic Mars-van Krevelen-type reactions in the liquid homogeneous phase.
- Intensification of Catalytic Oxidation with a T-junction Microchannel Reactor for Deep Desulfurization
- Epoxidation of olefins with hydrogen peroxide catalyzed by polyoxometalates
- Activation of molecular oxygen, polyoxometalates, and liquid-phase catalytic oxidation.
- Polyoxometalate-mediated electron transfer–oxygen transfer oxidation of cellulose and hemicellulose to synthesis gas
- The universal character of the Mars and Van Krevelen mechanism
- A molecular placeholder strategy to access a family of transition-metal-functionalized vanadium oxide clusters.
- Acetaldehyde from ethylene--a retrospective on the discovery of the Wacker process.
- Catalysis by Heteropoly Acids and Multicomponent Polyoxometalates in Liquid-Phase Reactions.
- Homogeneous catalysis by transition metal oxygen anion clusters
- Catalytic photochemical dehydrogenation of organic substrates by polyoxometalates
- Recent advances in transition metal catalyzed oxidation of organic substrates with molecular oxygen.
- New trends in polyoxometalate photoredox chemistry: from photosensitisation to water oxidation catalysis.
Cited by
- Dioxygen in Polyoxometalate Mediated Reactions.
- Non-Aqueous Microwave-Assisted Syntheses of Deca- and Hexa-Molybdovanadates.
- Nichtwässrige mikrowellengestützte Synthesen von Deca‐ und Hexamolybdovanadaten
- Polyoxovanadate-Alkoxide Clusters as a Redox Reservoir for Iron.
- A novel 12-molybdovanadate nanocluster: Synthesis, structure investigation and its application as an efficient heterogeneous sulfoxidation catalyst
- Light Sources for Photochemical Processes – Estimation of Technological Potentials
- In Situ Assembly, De‐Metalation and Induced Repair of a Copper‐Polyoxovanadate Oxidation Catalyst
- Detailed Kinetic Investigations on the Selective Oxidation of Biomass to Formic Acid (OxFA Process) Using Model Substrates and Real Biomass
- POMbranes: polyoxometalate-functionalized block copolymer membranes for oxidation catalysis
- Modular Polyoxometalate–Layered Double Hydroxides as Efficient Heterogeneous Sulfoxidation and Epoxidation Catalysts
- The Propensity of Uranium-Peroxide Systems to Preserve Nanosized Assemblies.
- Synthesis and photo-/electro-catalytic properties of Keggin polyoxometalate inorganic–organic hybrid layers based on d10 metal and rigid benzo-diazole/-triazole ligands
- Evolutionary Metal Oxide Clusters for Novel Applications: Toward High‐Density Data Storage in Nonvolatile Memories
- Understanding the Regioselectivity of Aromatic Hydroxylation over Divanadium-Substituted γ-Keggin Polyoxotungstate
- Measuring and Predicting the Extraction Behavior of Biogenic Formic Acid in Biphasic Aqueous/Organic Reaction Mixtures
- Fabrication of mesoporous POMs/SiO2 nanofibers through electrospinning for oxidative conversion of biomass by H2O2 and oxygen
- Aerobic Oxidation Catalysis by a Molecular Barium Vanadium Oxide.
- Polyoxometalate LUMO engineering: a strategy for visible-light-responsive aerobic oxygenation photocatalysts.
- Post-functionalization of a photoactive hybrid polyoxotungstate.
- Regenerating Spent Solutions of Vanadium-containing Heteropoly Acids in the Presence of Additives
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