Palladium(II)-catalyzed directed trifluoromethylthiolation of unactivated C(sp³)-H bonds.
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Summary
This work constitutes an example of the unactivated C(sp(3))-SCF3 bond formation by C-H activation offering a new access to relevant molecules.
- Type
- article
- Published
- 2015-03-30
- Cited by
- 93
- References
- 78
- OpenAlex
- https://openalex.org/W25791680
- Semantic Scholar
- https://api.semanticscholar.org/CorpusID:21468622
Keywords
Humanities, Art
References
- Cu(II)-catalyzed functionalizations of aryl C-H bonds using O2 as an oxidant.
- Direct Trifluoromethylthiolation Reactions: The “Renaissance” of an Old Concept
- Trifluoromethylthiolation of allylsilanes and silyl enol ethers with trifluoromethanesulfonyl hypervalent iodonium ylide under copper catalysis.
- Regio- and Stereocontrolled Nucleophilic Trifluoromethylthiolation of Morita–Baylis–Hillman Carbonates
- Access to Difluoromethylated Alkynes through the Castro–Stephens Reaction
- Rh(III)-catalyzed oxidative olefination of vinylic C-H bonds: efficient and selective access to di-unsaturated α-amino acid derivatives and other linear 1,3-butadienes.
- Ruthenium-catalyzed regioselective allylic trifluoromethylthiolation reaction.
- Copper-Promoted Sulfenylation of sp2 C-H Bonds
- Nickel-catalyzed thiolation of unactivated aryl C-H bonds: efficient access to diverse aryl sulfides.
- C–H Bond Activation at Palladium(IV) Centers
- Weakly Coordinating Directing Groups for Ruthenium(II)‐ Catalyzed CH Activation
- Understanding the Differential Performance of Rh2(esp)2 as a Catalyst for C–H Amination
- An electrophilic hypervalent iodine reagent for trifluoromethylthiolation.
- Copper-catalyzed intramolecular oxytrifluoromethylthiolation of unactivated alkenes.
- Recent advances in C-S bond formation via C-H bond functionalization and decarboxylation.
- Direct trifluoromethylthiolation of unactivated C(sp(3))-H using silver(I) trifluoromethanethiolate and potassium persulfate.
- Copper-mediated direct C(sp3)-H and C(sp2)-H acetoxylation.
- Challenge and progress: palladium-catalyzed sp3 C–H activation
- Catalysis for Fluorination and Trifluoromethylation
- Direct catalytic trifluoromethylthiolation of boronic acids and alkynes employing electrophilic shelf-stable N-(trifluoromethylthio)phthalimide.
Cited by
- Bidentate ligand 8-aminoquinoline-aided Pd-catalyzed diastereoselective β-arylation of the prochiral secondary sp3 C–H bonds of 2-phenylbutanamides and related aliphatic carboxamides
- Trifluoromethylation of thiophenols and thiols with sodium trifluoromethanesulfinate and iodine pentoxide
- Sandmeyer-Type Trifluoromethylthiolation and Trifluoromethylselenolation of (Hetero)Aromatic Amines Catalyzed by Copper.
- Palladium‐Catalysed Synthesis of α‐(Trifluoromethyl)styrenes by Means of Directed C–H Bond Functionalization
- Triphenylphosphine-Mediated Deoxygenative Reduction of CF3 SO2 Na and Its Application for Trifluoromethylthiolation of Aryl Iodides.
- Quantitative Scale for the Trifluoromethylthio Cation-Donating Ability of Electrophilic Trifluoromethylthiolating Reagents.
- Palladium N-heterocyclic carbene catalyzed regioselective thiolation of 1-aryl-3-methyl-1H-pyrazol-5(4H)-ones using aryl thiols
- Recent advances in transition metal (Pd, Ni)-catalyzed C(sp3)H bond activation with bidentate directing groups
- Oxidative trifluoromethylthiolation and thiocyanation of amines: a general approach to N–S bond formation
- State-of-the-Art in Electrophilic Trifluoromethylthiolation Reagents
- Mild metal-catalyzed C-H activation: examples and concepts.
- Enantiomerization of Allylic Trifluoromethyl Sulfoxides Studied by HPLC Analysis and DFT Calculations.
- Palladium-catalyzed directing group-assisted C8-triflation of naphthalenes.
- CH Bond Arylation of Diamondoids Catalyzed by Palladium(II) Acetate
- Palladium-Catalyzed Direct Arylation of C(sp(3))-H Bonds of α-Cyano Aliphatic Amides.
- Silver-mediated oxidative trifluoromethylthiolation of cycloalkanols by C–C bond cleavage: a regioselective approach to distally trifluoromethylthiolated ketones
- Catalytic C(sp(3) )-H Arylation of Free Primary Amines with an exo Directing Group Generated In Situ.
- New entries toward the synthesis of OCF3-containing molecules
- Pd(II)-Catalyzed Direct Sulfonylation of Unactivated C(sp(3))-H Bonds with Sodium Sulfinates.
- Rh(III)-Catalyzed Trifluoromethylthiolation of Indoles via C-H Activation.
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