Selective reductive cleavage of inert aryl C-O bonds by an iron catalyst.
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Summary
A highly selective iron-based catalytic system that enables the selective reductive cleavage of aryl C O bonds that employs iron(III) acetylacetonate ([Fe(acac)3]) as the catalyst precursor and LiAlH4 as the reducing agent is reported.
- Type
- article
- Published
- 2013-11-25
- Cited by
- 117
- References
- 49
- OpenAlex
- https://openalex.org/W24123387
- Semantic Scholar
- https://api.semanticscholar.org/CorpusID:42338772
Keywords
Geographic information system, Curriculum, GIS applications, Traditional knowledge GIS, Project commissioning
References
- Ni-catalyzed cleavage of aryl ethers in the aqueous phase.
- An efficient cleavage of the aryl ether C-O bond in supercritical carbon dioxide-water.
- Advances in Transition Metal (Pd, Ni, Fe)-Catalyzed Cross-Coupling Reactions Using Alkyl-Organometallics as Reaction Partners
- Guaiacol hydrodeoxygenation kinetics with catalyst deactivation taken into consideration
- A heterogeneous nickel catalyst for the hydrogenolysis of aryl ethers without arene hydrogenation.
- A review of the problem of distinguishing true homogeneous catalysis from soluble or other metal-particle heterogeneous catalysis under reducing conditions
- Nickel-catalyzed reductive cleavage of aryl-oxygen bonds in alkoxy- and pivaloxyarenes using hydrosilanes as a mild reducing agent.
- The catalytic valorization of lignin for the production of renewable chemicals.
- Gas-phase hydrodeoxygenation of guaiacol over iron-based catalysts. Effect of gases composition, iron load and supports (silica and activated carbon)
- C-H activation for the construction of C-B bonds.
- Hydrogenolysis of lignosulfonate into phenols over heterogeneous nickel catalysts.
- Effect of catalyst composition on the hydrogenolysis of anisole
- Transition-metal-catalyzed Suzuki-Miyaura cross-coupling reactions: a remarkable advance from palladium to nickel catalysts.
- Hydrodeoxygenation of guaiacol over carbon-supported molybdenum nitride catalysts: Effects of nitriding methods and support properties
- Selective, Nickel-Catalyzed Hydrogenolysis of Aryl Ethers
- Catalytic C-O Bond Cleavage of 2-Aryloxy-1-arylethanols and Its Application to the Depolymerization of Lignin Related Polymers
- Studies on the catalysts for coal liquefaction, I. Specific behaviours of various catalysts in the hydrogenolysis of model compounds☆☆☆
- Mild iridium-catalyzed borylation of arenes. High turnover numbers, room temperature reactions, and isolation of a potential intermediate.
- Mechanism of the mild functionalization of arenes by diboron reagents catalyzed by iridium complexes. Intermediacy and chemistry of bipyridine-ligated iridium trisboryl complexes.
- Hydrogenation and cleavage of the C-O bonds in the lignin model compound phenethyl phenyl ether over a nickel-based catalyst
Cited by
- Scope and Mechanistic Analysis for Chemoselective Hydrogenolysis of Carbonyl Compounds Catalyzed by a Cationic Ruthenium Hydride Complex with a Tunable Phenol Ligand.
- Selective activation of the C–O bonds in lignocellulosic biomass for the efficient production of chemicals
- Fragmentation of structural units of lignin promoted by persulfate through selective C–C cleavage under mild conditions
- Metal catalyzed defunctionalization reactions.
- Reductive cleavage of inert aryl C-O bonds to produce arenes.
- Oxidative conversion of lignin and lignin model compounds catalyzed by CeO2-supported Pd nanoparticles
- Selective oxidative C–C bond cleavage of a lignin model compound in the presence of acetic acid with a vanadium catalyst
- Precise oxygen scission of lignin derived aryl ethers to quantitatively produce aromatic hydrocarbons in water
- Selective hydrogenolysis of phenols and phenyl ethers to arenes through direct C–O cleavage over ruthenium–tungsten bifunctional catalysts
- Regio- and stereochemistry of Na-mediated reductive cleavage of alkyl aryl ethers
- Highly selective reductive cleavage of aromatic carbon-oxygen bonds catalyzed by a cobalt compound
- Catalytic Hydrogenolysis of Aryl Ethers: A Key Step in Lignin Valorization to Valuable Chemicals
- Novel Catalytic Systems to Convert Chitin and Lignin into Valuable Chemicals
- Mild and Robust Redox-Neutral Pd/C-Catalyzed Lignol β-O-4' Bond Cleavage Through a Low-Energy-Barrier Pathway.
- Rhodium-mediated hydrogenolysis/hydrolysis of the aryl ether bond in supercritical carbon dioxide/water: an experimental and theoretical approach
- Direct and selective hydrogenolysis of arenols and aryl methyl ethers
- Iron catalysis in organic synthesis.
- Metal-catalyzed activation of ethers via C-O bond cleavage: a new strategy for molecular diversity.
- From models to lignin: Transition metal catalysis for selective bond cleavage reactions
- Promotional effect of Fe on performance of Ni/SiO2 for deoxygenation of methyl laurate as a model compound to hydrocarbons
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