Direct C-N coupling of imidazoles and benzylic compounds via iron-catalyzed oxidative activation of C-H bonds.
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Summary
Iron-catalyzed direct C-N bond formation between imidazoles and benzylic hydrocarbons is described, using an inexpensive iron catalyst-oxidant system that is suitable for the coupling of a range of Benzylic C-H bonds with various imidAZoles.
- Type
- article
- Published
- 2011-08-16
- Cited by
- 104
- References
- 49
- OpenAlex
- https://openalex.org/W21797284
- Semantic Scholar
- https://api.semanticscholar.org/CorpusID:22875378
Keywords
Business
References
- Complexes with poly(N-heterocyclic carbene) ligands: structural features and catalytic applications.
- Metal-catalyzed oxidations of C-H to C-N bonds.
- Cross-dehydrogenative coupling reactions of sp3-hybridized C-H bonds.
- Efficient intermolecular iron-catalyzed amidation of C-H bonds in the presence of N-bromosuccinimide.
- Iron-Catalyzed CN Cross-Coupling of Sulfoximines with Aryl Iodides
- Cross-dehydrogenative coupling (CDC): exploring C-C bond formations beyond functional group transformations.
- Aromatic amination/imination approach to chiral benzimidazoles.
- DDQ-mediated direct cross-dehydrogenative-coupling (CDC) between benzyl ethers and simple ketones.
- Catalytic C-H amination: recent progress and future directions.
- N-heterocyclic carbenes in late transition metal catalysis.
- Ionic liquids and their interaction with cellulose.
- Autoxidative carbon-carbon bond formation from carbon-hydrogen bonds.
- Copper-catalyzed amination of primary benzylic C-H bonds with primary and secondary sulfonamides.
- Iron-catalyzed C-C bond formation by direct functionalization of C-H bonds adjacent to heteroatoms.
- Recyclable heterogeneous iron catalyst for C-N cross-coupling under ligand-free conditions.
- Transition-metal-free intermolecular amination of sp3 C-H bonds with sulfonamides.
- Copper‐Catalyzed Highly Regioselective Oxidative CH Bond Amidation of 2‐Arylpyridine Derivatives and 1‐Methylindoles
- Ionic liquids in heterocyclic synthesis.
- Copper-catalyzed cross dehydrogenative coupling reactions of tertiary amines with ketones or indoles.
- Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion
Cited by
- Cross dehydrogenative coupling (CDC) of aldehydes with N-hydroxyimides by visible light photoredox catalysis
- I2-Catalyzed diamination of acetyl-compounds for the synthesis of multi-substituted imidazoles
- Reusable ionic liquid-catalyzed oxidative coupling of azoles and benzylic compounds via sp(3) C-N bond formation under metal-free conditions.
- Iron-Catalyzed Esterification of Benzyl CH Bonds to Form α-Keto Benzyl Esters
- Utilization of methylarenes as versatile building blocks in organic synthesis.
- Iron-catalyzed benzylation of 1,3-dicarbonyl compounds by simple toluene derivatives
- DDQ-promoted direct transformation of benzyl hydrocarbons to amides via tandem reaction of the CDC reaction and Beckmann rearrangement.
- Synthesis of tert‐Butyl Peroxyacetals from Benzyl, Allyl, or Propargyl Ethers via Iron‐Promoted CH Bond Functionalization
- Synthesis of C8-N9 annulated purines by iron-catalyzed C-H amination.
- Copper-catalyzed decarboxylative C(sp2)-C(sp3) coupling reactions via radical mechanism.
- Domino Cross Dehydrogenative Coupling of 2-Aryl Acetals with Ketones Using DDQ as Oxidant and Reactant Precursor
- Metal-free, highly efficient organocatalytic amination of benzylic C-H bonds.
- Practical Synthesis of Polysubstituted Imidazoles via Iodine-Catalyzed Aerobic Oxidative Cyclization of Aryl Ketones and Benzylamines.
- Metal-free oxidative synthesis of quinazolinones via dual amination of sp3 C-H bonds.
- Copper-catalyzed oxidative benzylarylation of acrylamides by benzylic C-H bond functionalization for the synthesis of oxindoles.
- Exploring the coordination chemistry of 1-benzoyl-4,5-dihydro-3,5-bis(trifluoromethyl)-1H-pyrazol-5-ol to copper
- A facile approach to synthesize 3,5-disubstituted-1,2,4-oxadiazoles via copper-catalyzed-cascade annulation of amidines and methylarenes.
- Iron(III)‐Catalyzed Direct N‐Alkylation of Azoles via Oxidative Transformation of sp3 CH Bonds under Solvent‐Free Conditions
- Iron catalysis in organic synthesis.
- Copper-Catalyzed α-Benzylation of Enones via Radical-Triggered Oxidative Coupling of Two C–H Bonds
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