Effects of chemical structure on the thermodynamic efficiency of radical chain carriers for organic synthesis.
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Summary
The broad finding from this work is that successful chain carriers generally maximize the strength of their halide (versus hydride bonds) through charge-shift bonding, and the thermodynamic efficiency of a chain carrier tends to increase down the periodic table, and also with the inclusion of stronger electron donating substituents.
- Type
- article
- Published
- 2011-01-31
- Cited by
- 18
- References
- 39
- OpenAlex
- https://openalex.org/W21280598
- Semantic Scholar
- https://api.semanticscholar.org/CorpusID:21206845
Keywords
Humanities, Art
References
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- Why are organotin hydride reductions of organic halides so frequently retarded? Kinetic studies, analyses, and a few remedies.
- Predicting pKa in Implicit Solvents: Current Status and Future Directions*
- Performance of ONIOM in the investigations of tri-n-butyltin compounds
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- Influence of Electronic Effects over the Reactivity of Triazolylidene-Boryl Radicals. Consequences for the use of NHC-Boranes in Organic and Polymer Synthesis
- Reaction mechanisms: radical and radical ion reactions
- Linear-free energy relationships for modeling structure-reactivity trends in controlled radical polymerization
- Hydrogen Atom Abstraction Thermodynamics of a μ-1,2-Superoxo Dicopper(II) Complex.
- Radical Arene Addition vs Radical Reduction: Why Organometal Hydride Chain Reactions Stop and How To Make Them Go.
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- Monovalent Nickel-Mediated Radical Formation: A Concerted Halogen-Atom Dissociation Pathway Determined by Electroanalytical Studies
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- Radical reactivity by computation and experiment
- Silicon-Centered Radicals
- Persistent and Stable Silyl Radicals
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