How intimate contact with nanoporous carbon benefits the reversible hydrogen desorption from NaH and NaAlH4.
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Summary
The kinetics and thermodynamics for the reversible hydrogen desorption from NaH (and NaH derived from NaAlH4) are greatly improved by nanosizing and providing close contact to a porous carbon matrix.
- Type
- article
- Published
- 2009-10-13
- Cited by
- 63
- References
- 20
- OpenAlex
- https://openalex.org/W19826688
- Semantic Scholar
- https://api.semanticscholar.org/CorpusID:37054690
Keywords
Extension (predicate logic), Mathematics, Inequality, Markov chain, Computer science
References
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- Sodium alanate nanoparticles--linking size to hydrogen storage properties.
- Sodium reactivity with anthracitic carbons at 700°C
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- Size effects on the hydrogen storage properties of nanostructured metal hydrides: A review
- Intercalation reactions and carbide formation in graphite-lithium system
- Modeling the sorption dynamics of NaH using a reactive force field.
- Co-intercalation into graphite of lithium and sodium with an alkaline earth metal
- Metal hydride materials for solid hydrogen storage: a review
- Decomposition reactions for NaAlH4, Na3AlH6, and NaH: First-principles study
- Hydrogen-alkali-metal-graphite ternary intercalation compounds
- Preparation and characterization of sodium-graphite intercalation compounds
- DTA study of the kinetics of sodium hydride decomposition
- Hydrogen storage in magnesium clusters: quantum chemical study.
- How carbon affects hydrogen desorption in NaAlH4 and Ti-doped NaAlH4
- Metal-doped sodium aluminium hydrides as potential new hydrogen storage materials
- Hydrogen-storage materials for mobile applications
- Complex hydrides for hydrogen storage.
- The Mechanisms of Lithium and Sodium Insertion in Carbon Materials
Cited by
- Mechanochemically driven iodination of activated charcoal for metal-free electrocatalyst for fuel cells and hybrid Li-air cells
- NaBH4 in “Graphene Wrapper:” Significantly Enhanced Hydrogen Storage Capacity and Regenerability through Nanoencapsulation
- Stabilization of NaZn(BH4)3via nanoconfinement in SBA-15 towards enhanced hydrogen release
- Pitfalls in the characterization of sulfur/carbon nanocomposite materials for lithium–sulfur batteries
- Nanoconfinement effects in energy storage materials.
- Influence of nano-confinement on the thermodynamics and dehydrogenation kinetics of metal hydrides
- A step forward to the dehydrogenation reversibility of amine-borane adducts by coupling sodium and hydrocarbon groups
- Nanoconfined light metal hydrides for reversible hydrogen storage
- The impact of carbon materials on the hydrogen storage properties of light metal hydrides
- Comparison of hydrogen cycling kinetics in NaAlH4–carbon aerogel composites synthesized by melt infusion or ball milling
- Improved hydrogen sorption performance of NbF5-catalysed NaAlH4
- Identifying the nature of interaction between LiBH4 and two-dimensional substrates: DFT study with van der Waals correction
- Catalytic nanoconfinement effect of in-situ synthesized Ni-containing mesoporous carbon scaffold (Ni-MCS) on the hydrogen storage properties of LiAlH4
- Improved hydrogen storage kinetics of nanoconfined NaAlH₄ catalyzed with TiCl₃ nanoparticles.
- Enhanced hydrogen storage properties of NaAlH4 co-catalysed with niobium fluoride and single-walled carbon nanotubes
- Destabilisation of complex hydrides through size effects.
- Synthesis, characterization, and reversible hydrogen sorption study of sodium-doped fullerene
- Nucleation and growth mechanisms of nano magnesium hydride from the hydrogen sorption kinetics.
- Melt Infiltration: an Emerging Technique for the Preparation of Novel Functional Nanostructured Materials
- NaAlH4 confined in ordered mesoporous carbon
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