Bidirectional synthesis of the central amino acid of chloptosin.
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Summary
This C(2)-symmetrical amino acid was synthesized by using a 14-step route, in which a Zinin benzidine rearrangement, intramolecular Heck reaction, and selenocyclization and oxidative deselenation served as key steps.
- Type
- article
- Published
- 2006-09-14
- Cited by
- 24
- References
- 27
- OpenAlex
- https://openalex.org/W17020336
- Semantic Scholar
- https://api.semanticscholar.org/CorpusID:38736648
Keywords
Transformational leadership, Health care, Business, Public relations, Knowledge management
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- On the Reaction of Tryptophan Derivatives with N-Phenylselenyl Phthalimide: The Nature of the Kinetic and Thermodynamic Hexahydropyrrolo[2,3-b]indole Products. Alkylation of Tryptophan with Inversion of Configuration
Cited by
- Total synthesis of chloptosin.
- Cyclopropylazetoindolines as precursors to C(3)-quaternary-substituted indolines.
- Efficient assembly of 3-substituted oxindole-based isoxazolines leading to the synthesis of (±)-flustraminol-B and related natural product building blocks
- Schischkiniin support studies: synthetic access to 1,1'-bisindoles.
- Palladium Catalysts: Synthesis of Five-Membered N-Heterocycles Fused with Other Heterocycles
- Recent Advances in Organoselenium Chemistry
- Selenenylations of alkenes with styrene nucleophiles
- Intraannular Savige-Fontana reaction: one-step conversion of one class of monocyclic peptides into another class of bicyclic peptides.
- Biosynthesis of himastatin: assembly line and characterization of three cytochrome P450 enzymes involved in the post-tailoring oxidative steps.
- Total synthesis of chloptosin: a dimeric cyclohexapeptide.
- Bidirectional racemic synthesis of the biologically active quinone cardinalin 3.
- Piperazic acid-containing natural products: isolation, biological relevance and total synthesis.
- Advances in Dearomatization Strategies of Indoles
- Stereoselective synthesis of brevianamide E.
- The 4.4′-benzidine rearrangement of 4-alkyl substituted hydrazobenzenes
- α-Amino acids with electrically charged and polar uncharged side chains as chiral synthon: Application to the synthesis of bioactive alkaloids (1996-Dec, 2013)
- Recent advances in direct dehydrogenative biphenyl couplings
- Applications of allylamines for the syntheses of aza-heterocycles ☆
- C(sp3)H/N(sp2) cross-coupling reaction for the synthesis of tertiary arylamines via fluxional SOX·Pd(II) catalysis
- Stereoselective Reactions of Organoselenium Reagents Including Catalysis
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