CH/π interactions involving aromatic amino acids: Refinement of the CHARMM tryptophan force field

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Summary

Comparisons with published data indicate that the MP2/cc‐pVTZ level of theory is suitable for calculations of CH/π interaction, including the T‐shape benzene dimer, and in the majority of orientations, CHARMM22 reproduces the preferred binding modes, with excellent agreement for the benzeneDimer.

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Published
2005-11-15
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