Understanding and exploiting C–H bond activation
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Summary
The recent development of promising catalytic systems highlights the potential of organometallic chemistry for useful C–H bond activation strategies that will ultimately allow us to exploit Earth's alkane resources more efficiently and cleanly.
- Type
- article
- Published
- 2002-05-30
- Cited by
- 2,094
- References
- 73
- OpenAlex
- https://openalex.org/W12037558
- Semantic Scholar
- https://api.semanticscholar.org/CorpusID:4373340
Keywords
Materials science, Condensed matter physics, Physics
References
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- Principles and applications of organotransition metal chemistry
- Activation of carbon-hydrogen bonds in saturated hydrocarbons on photolysis of (.eta.5-C5Me5)(PMe3)IrH2. Relative rates of reaction of the intermediate with different types of carbon-hydrogen bonds and functionalization of the metal-bound alkyl groups
- Methane exchange reactions of lanthanide and early-transition-metal methyl complexes
- Activation of the C-H Bonds in Neopentane and Neopentane-d12 by (.eta.5-C5(CH3)5)Rh(CO)2: Spectroscopic and Temporal Resolution of Rhodium-Krypton and Rhodium-Alkane Complex Intermediates
- Activation of Methane and Ethane and Their Selective Oxidation to the Alcohols in Protic Media
- Activation of saturated hydrocarbons by metal complexes in solution
- Methane and benzene activation via transient (tert-Bu3SiNH)2Zr:NSi-tert-Bu3
- Generation, alkyne cycloaddition, arene carbon-hydrogen activation, nitrogen-hydrogen activation and dative ligand trapping reactions of the first monomeric imidozirconocene (Cp2Zr:NR) complexes
- OXIDATION OF DIMETHYLPLATINUM(II) COMPLEXES WITH DIOXYGEN
- Catalytic Shilov chemistry: platinum chloride-catalyzed oxidation of terminal methyl groups by dioxygen.
- Coordination chemistry of dihydrogen
- Oxidative addition of the carbon-hydrogen bonds of neopentane and cyclohexane to a photochemically generated iridium(I) complex
- Efficient thermochemical alkane dehydrogenation and isomerization catalyzed by an iridium pincer complex
- DIRECT OBSERVATION OF A TRANSITION METAL ALKANE COMPLEX, CPRE(CO)2(CYCLOPENTANE), USING NMR SPECTROSCOPY
Cited by
- Free radical versus electron-transfer routes of oxidation of hydrocarbons by laccase/mediator systems. Catalytic or stoichiometric procedures
- Preparation of indoles via iron catalyzed direct oxidative coupling.
- An iridium-mediated C-H activation/CO2-carboxylation reaction of 1,1-bisdiphenylphosphinomethane.
- How is methane formed and oxidized reversibly when catalyzed by Ni-containing methyl-coenzyme M reductase?
- Computational study of the coordination of methane to first row transition metal dication complexes.
- Purinyl N1-Directed Aromatic C–H Oxidation in 6-Arylpurines and 6-Arylpurine Nucleosides
- C-H functionalization: thoroughly tuning ligands at a metal ion, a chemist can greatly enhance catalyst's activity and selectivity.
- Photoredox α-Vinylation of α-Amino Acids and N-Aryl Amines
- Rh2(esp)2-catalyzed allylic and benzylic oxidations.
- Fungal cytochrome P450 monooxygenases of Fusarium oxysporum for the synthesis of ω-hydroxy fatty acids in engineered Saccharomyces cerevisiae
- A Hydrazone-Based Covalent Organic Framework as an Efficient and Reusable Photocatalyst for the Cross-Dehydrogenative Coupling Reaction of N-Aryltetrahydroisoquinolines.
- A Facile Steam Reforming Strategy to Delaminate Layered Carbon Nitride Semiconductors for Photoredox Catalysis.
- Tritopic NHC Precursors: Unusual Nickel Reactivity and Ethylene Insertion into a C(sp3 )-H Bond.
- Reactions of organoplatinum complexes with dimethylamine-borane
- Directed Evolution of Cytochrome P450 for Small Alkane Hydroxylation
- Coexistence of Lewis acid and base functions: a generalized view of the frustrated Lewis pair concept with novel implications for reactivity.
- Palladium-Catalyzed Synthesis of a Benzofuran: A Case Study in the Development of a Green Chemistry Laboratory Experiment
- Computational Studies of Inorganic Systems with a Multiscale Modeling Approach: From Atomistic to Continuum Scale
- Catalysts for C–H functionalization: Platinum, gold and even nanodiamonds
- Mechanistic considerations on catalytic H/D exchange mediated by organometallic transition metal complexes
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