Selective catalysis for cellulose conversion to lactic acid and other α-hydroxy acids.
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Summary
This review discusses topical chemical routes and their catalysis for the conversion of cellulose, hexoses, and smaller carbohydrates to lactic acid and other useful α-hydroxy acids and attempts to guide the reader through the complex reaction networks encountered when synthetic lactates from carbohydrate biomass are targeted.
- Type
- review
- Published
- 2014-01-01
- Cited by
- 53
- References
- 170
- OpenAlex
- https://openalex.org/W401451
- Semantic Scholar
- https://api.semanticscholar.org/CorpusID:206609090
Keywords
Chemistry, Commodity chemicals, Glycolic acid, Lactic acid, Cellulose
References
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- Mechanism of lactic acid formation catalyzed by tetraamine rhodium(III) complexes
- Top chemical opportunities from carbohydrate biomass: a chemist's view of the Biorefinery.
- Advanced Organic Chemistry: Reactions, Mechanisms, and Structure
- March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure
- Formation of 2,3-Pentanedione from Lactic Acid over Supported Phosphate Catalysts
- Selective Catalysis of Lactic Acid to Produce Commodity Chemicals
- Reaction and Kinetic Studies of Lactic Acid Conversion over Alkali-Metal Salts
- Brock Biology of Microorganisms
- Mechanocatalytic depolymerization of cellulose combined with hydrogenolysis as a highly efficient pathway to sugar alcohols
- Lactic acid as a platform chemical in the biobased economy: the role of chemocatalysis
- A Kinetic Model for the Esterification of Lactic Acid and Its Oligomers
- Production of platform chemicals and synthesis gas from biomass.
- Bridging racemic lactate esters with stereoselective polylactic acid using commercial lipase catalysis
- Efficient hydrolytic hydrogenation of cellulose in the presence of Ru-loaded zeolites and trace amounts of mineral acid.
- Chemocatalytic conversion of cellulose: opportunities, advances and pitfalls
- Conversion of biomass to 1,2-propanediol by selective catalytic hydrogenation of lactic acid over silica-supported copper
- Conversion of Sugars to Lactic Acid Derivatives Using Heterogeneous Zeotype Catalysts
- Hydrolytic hydrogenation of cellulose with hydrotreated caesium salts of heteropoly acids and Ru/C
- Potassium modified NaY: A selective and durable catalyst for dehydration of lactic acid to acrylic acid
Cited by
- Nanoporous catalysts for biomass conversion
- Design of Lewis-acid centres in zeolitic matrices for the conversion of renewables.
- Cooperative Catalysis for Multistep Biomass Conversion with Sn/Al Beta Zeolite
- Chemical conversion pathways for carbohydrates
- The Effect of Adsorbed Molecule Gas-Phase Deprotonation Enthalpy on Ion Exchange in Sodium Exchanged Zeolites: An In Situ FTIR Investigation
- One-pot transformation of polysaccharides via multi-catalytic processes
- Direct catalytic conversion of cellulose to liquid straight-chain alkanes
- Chemocatalysis of sugars to produce lactic acid derivatives on zeolitic imidazolate frameworks
- Catalytic dehydration of methyl lactate: Reaction mechanism and selectivity control
- Lactide Synthesis and Chirality Control for Polylactic acid Production.
- Robust Iridium Coordination Polymers: Highly Selective, Efficient, and Recyclable Catalysts for Oxidative Conversion of Glycerol to Potassium Lactate with Dihydrogen Liberation
- Selective Chemical Conversion of Sugars in Aqueous Solutions without Alkali to Lactic Acid Over a Zn-Sn-Beta Lewis Acid-Base Catalyst
- Copper-catalyzed retro-aldol reaction of β-hydroxy ketones or nitriles with aldehydes: chemo- and stereoselective access to (E)-enones and (E)-acrylonitriles.
- Selectivity Control in the Catalytic Dehydration of Methyl Lactate: The Effect of Pyridine
- Efficient one-pot fructose to DFF conversion using sulfonated magnetically separable MOF-derived Fe3O4 (111) catalysts
- Catalyst Deactivation in Pyridine-Assisted Selective Dehydration of Methyl Lactate on NaY
- Lewis acid catalysis on single site Sn centers incorporated into silica hosts
- Borate-Stabilized Transformation of C6 Aldose to C4 Aldose
- Bio-based amines through sustainable heterogeneous catalysis
- Bio-based acrylic acid from sugar via propylene glycol and allyl alcohol
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